Abstract
A Laplace transform-based procedure was proposed to calculate the effective time constant for a class of nonlinear diffusion problems. The governing mathematical representation was first estimated with a linear model by omitting the nonlinear term. The solution to this problem was later introduced into the original equation, which was solved with Laplace transforms, resulting in a first-order approximation of the real system's behavior. A time constant was calculated using frequency-domain expressions. Two case studies were considered to illustrate the methodology. As the rate of heat supplied to a rod is raised, the speed at which the temperature reached an equilibrium value decreased. Increasing the maximum velocity in reaction-diffusion transport by a factor of three lowered the time constant by only 1.7%. The applications of this method range from biosensor dynamics to process control.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 719-736 |
| Number of pages | 18 |
| Journal | Chemical Engineering Communications |
| Volume | 201 |
| Issue number | 6 |
| DOIs | |
| State | Published - Jun 2014 |
All Science Journal Classification (ASJC) codes
- General Chemistry
- General Chemical Engineering
Keywords
- Diffusion
- Effective time constant
- Heat transfer
- Kinetics
- Mathematical modeling
- Nonlinear dynamics