Aerosol synthesis of cargo-filled graphene nanosacks

Yantao Chen; Fei Guo; Ashish Jachak; Sang Pil Kim; Dibakar Datta; Jingyu Liu; Indrek Kulaots; Charles Vaslet; Hee Dong Jang; Jiaxing Huang; Agnes Kane; Vivek B. Shenoy; Robert H. Hurt

doi:10.1021/nl2045952

Aerosol synthesis of cargo-filled graphene nanosacks

Yantao Chen, Fei Guo, Ashish Jachak, Sang Pil Kim, Dibakar Datta, Jingyu Liu, Indrek Kulaots, Charles Vaslet, Hee Dong Jang, Jiaxing Huang, Agnes Kane, Vivek B. Shenoy, Robert H. Hurt

Research output: Contribution to journal › Article › peer-review

187 Scopus citations

Abstract

Water microdroplets containing graphene oxide and a second solute are shown to spontaneously segregate into sack-cargo nanostructures upon drying. Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the receding air-water interface, followed by capillary collapse. Cargo-filled graphene nanosacks can be nanomanufactured by a simple, continuous, scalable process and are promising for many applications where nanoscale materials should be isolated from the environment or biological tissue.

Original language	English (US)
Pages (from-to)	1996-2002
Number of pages	7
Journal	Nano Letters
Volume	12
Issue number	4
DOIs	https://doi.org/10.1021/nl2045952
State	Published - Apr 11 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Bioengineering
General Chemistry
General Materials Science
Condensed Matter Physics
Mechanical Engineering

Keywords

Graphene
biocompatibility
core-shell structures
encapsulation
folding
graphene oxide

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10.1021/nl2045952

Cite this

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title = "Aerosol synthesis of cargo-filled graphene nanosacks",

abstract = "Water microdroplets containing graphene oxide and a second solute are shown to spontaneously segregate into sack-cargo nanostructures upon drying. Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the receding air-water interface, followed by capillary collapse. Cargo-filled graphene nanosacks can be nanomanufactured by a simple, continuous, scalable process and are promising for many applications where nanoscale materials should be isolated from the environment or biological tissue.",

keywords = "Graphene, biocompatibility, core-shell structures, encapsulation, folding, graphene oxide",

author = "Yantao Chen and Fei Guo and Ashish Jachak and Kim, \{Sang Pil\} and Dibakar Datta and Jingyu Liu and Indrek Kulaots and Charles Vaslet and Jang, \{Hee Dong\} and Jiaxing Huang and Agnes Kane and Shenoy, \{Vivek B.\} and Hurt, \{Robert H.\}",

year = "2012",

month = apr,

day = "11",

doi = "10.1021/nl2045952",

language = "English (US)",

volume = "12",

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journal = "Nano Letters",

issn = "1530-6984",

publisher = "American Chemical Society",

number = "4",

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TY - JOUR

T1 - Aerosol synthesis of cargo-filled graphene nanosacks

AU - Chen, Yantao

AU - Guo, Fei

AU - Jachak, Ashish

AU - Kim, Sang Pil

AU - Datta, Dibakar

AU - Liu, Jingyu

AU - Kulaots, Indrek

AU - Vaslet, Charles

AU - Jang, Hee Dong

AU - Huang, Jiaxing

AU - Kane, Agnes

AU - Shenoy, Vivek B.

AU - Hurt, Robert H.

PY - 2012/4/11

Y1 - 2012/4/11

N2 - Water microdroplets containing graphene oxide and a second solute are shown to spontaneously segregate into sack-cargo nanostructures upon drying. Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the receding air-water interface, followed by capillary collapse. Cargo-filled graphene nanosacks can be nanomanufactured by a simple, continuous, scalable process and are promising for many applications where nanoscale materials should be isolated from the environment or biological tissue.

AB - Water microdroplets containing graphene oxide and a second solute are shown to spontaneously segregate into sack-cargo nanostructures upon drying. Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the receding air-water interface, followed by capillary collapse. Cargo-filled graphene nanosacks can be nanomanufactured by a simple, continuous, scalable process and are promising for many applications where nanoscale materials should be isolated from the environment or biological tissue.

KW - Graphene

KW - biocompatibility

KW - core-shell structures

KW - encapsulation

KW - folding

KW - graphene oxide

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U2 - 10.1021/nl2045952

DO - 10.1021/nl2045952

M3 - Article

C2 - 22429091

AN - SCOPUS:84859699752

SN - 1530-6984

VL - 12

SP - 1996

EP - 2002

JO - Nano Letters

JF - Nano Letters

IS - 4

ER -

Aerosol synthesis of cargo-filled graphene nanosacks

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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