Asymmetry in the metal:ammonia phase diagram

G. A. Thomas

doi:10.1021/j150661a014

Asymmetry in the metal:ammonia phase diagram

G. A. Thomas

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

We compare the liquid-gas phase diagram of metals in NH₃ with electron-hole liquids and doped semiconductors. Both the metal:NH₃ and e-h liquid-phase diagrams are asymmetric compared to those of simple fluids. The asymmetry appears to result from changes with density in the range of interaction between the positive and negative species, as emphasized by Mott, although the metal-insulator transition may be at zero temperature, as in Si:P.

Original language	English (US)
Pages (from-to)	3749-3751
Number of pages	3
Journal	Journal of physical chemistry
Volume	88
Issue number	17
DOIs	https://doi.org/10.1021/j150661a014
State	Published - 1984
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Engineering
Physical and Theoretical Chemistry

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10.1021/j150661a014

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title = "Asymmetry in the metal:ammonia phase diagram",

abstract = "We compare the liquid-gas phase diagram of metals in NH3 with electron-hole liquids and doped semiconductors. Both the metal:NH3 and e-h liquid-phase diagrams are asymmetric compared to those of simple fluids. The asymmetry appears to result from changes with density in the range of interaction between the positive and negative species, as emphasized by Mott, although the metal-insulator transition may be at zero temperature, as in Si:P.",

author = "Thomas, {G. A.}",

year = "1984",

doi = "10.1021/j150661a014",

language = "English (US)",

volume = "88",

pages = "3749--3751",

journal = "Journal of physical chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "17",

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TY - JOUR

T1 - Asymmetry in the metal:ammonia phase diagram

AU - Thomas, G. A.

PY - 1984

Y1 - 1984

N2 - We compare the liquid-gas phase diagram of metals in NH3 with electron-hole liquids and doped semiconductors. Both the metal:NH3 and e-h liquid-phase diagrams are asymmetric compared to those of simple fluids. The asymmetry appears to result from changes with density in the range of interaction between the positive and negative species, as emphasized by Mott, although the metal-insulator transition may be at zero temperature, as in Si:P.

AB - We compare the liquid-gas phase diagram of metals in NH3 with electron-hole liquids and doped semiconductors. Both the metal:NH3 and e-h liquid-phase diagrams are asymmetric compared to those of simple fluids. The asymmetry appears to result from changes with density in the range of interaction between the positive and negative species, as emphasized by Mott, although the metal-insulator transition may be at zero temperature, as in Si:P.

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UR - http://www.scopus.com/inward/citedby.url?scp=33845469413&partnerID=8YFLogxK

U2 - 10.1021/j150661a014

DO - 10.1021/j150661a014

M3 - Article

AN - SCOPUS:33845469413

SN - 0022-3654

VL - 88

SP - 3749

EP - 3751

JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 17

ER -

Asymmetry in the metal:ammonia phase diagram

Abstract

All Science Journal Classification (ASJC) codes

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