Cesium Lead Bromides—Structural, Electronic and Optical Properties

Aneer Lamichhane, N. M. Ravindra

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

In recent years, it has been found that lowering the dimensionality of halide perovskites leads to enhanced photoluminescence and stability than their three-dimensional counterparts. Further, the change in the dimensionality of an inorganic halide perovskite can evoke surprising ramifications to its intrinsic behavior. The dimensionality in perovskites is governed by its octahedral cages. In zero-dimensional perovskites, the octahedral cages are discrete, whereas in two-dimensional perovskites, they are connected with one another resulting in the formation of a layer. Likewise, in three-dimensional perovskites, the octahedral cages share the corner atoms with each other. This study describes the two-dimensional counterpart of cesium lead bromide perovskites. The structural, electronic and optical properties, in conjunction with their three-dimensional structure, are presented. The emergence of new physical phenomena with respect to the decreasing dimensionality of cesium lead bromide perovskites is analyzed.

Original languageEnglish (US)
Title of host publicationTMS 2021 150th Annual Meeting and Exhibition Supplemental Proceedings
PublisherSpringer Science and Business Media Deutschland GmbH
Pages3-14
Number of pages12
ISBN (Print)9783030652609
DOIs
StatePublished - 2021
Event150th Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2021 - Pittsburgh, United States
Duration: Mar 15 2021Mar 18 2021

Publication series

NameMinerals, Metals and Materials Series
Volume5
ISSN (Print)2367-1181
ISSN (Electronic)2367-1696

Conference

Conference150th Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2021
CountryUnited States
CityPittsburgh
Period3/15/213/18/21

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy Engineering and Power Technology
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

Keywords

  • CsPbBr, CsPbBr, CsPbBr
  • Electronic properties
  • Optical properties
  • Structural properties

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