Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

Chi Chen; Muhammad Boota; Xiuqiang Xie; Mengqiang Zhao; Babak Anasori; Chang E. Ren; Ling Miao; Jianjun Jiang; Yury Gogotsi

doi:10.1039/c7ta00149e

Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

Chi Chen, Muhammad Boota, Xiuqiang Xie, Mengqiang Zhao, Babak Anasori, Chang E. Ren, Ling Miao, Jianjun Jiang, Yury Gogotsi

Research output: Contribution to journal › Article › peer-review

152 Scopus citations

Abstract

In situ polymerization of 3,4-ethylenedioxythiophene (EDOT) is achieved on the surface of 2D Ti₃C₂T_x MXene without using any oxidant, resulting in improved lithium ion storage capability of Ti₃C₂T_x/poly-EDOT hybrids. A combined experimental and theoretical study revealed the mechanism of charge-transfer-induced polymerization of EDOT, which can be extended to other similar polymers.

Original language	English (US)
Pages (from-to)	5260-5265
Number of pages	6
Journal	Journal of Materials Chemistry A
Volume	5
Issue number	11
DOIs	https://doi.org/10.1039/c7ta00149e
State	Published - 2017
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry
Renewable Energy, Sustainability and the Environment
General Materials Science

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10.1039/c7ta00149e

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title = "Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers",

abstract = "In situ polymerization of 3,4-ethylenedioxythiophene (EDOT) is achieved on the surface of 2D Ti3C2Tx MXene without using any oxidant, resulting in improved lithium ion storage capability of Ti3C2Tx/poly-EDOT hybrids. A combined experimental and theoretical study revealed the mechanism of charge-transfer-induced polymerization of EDOT, which can be extended to other similar polymers.",

author = "Chi Chen and Muhammad Boota and Xiuqiang Xie and Mengqiang Zhao and Babak Anasori and Ren, {Chang E.} and Ling Miao and Jianjun Jiang and Yury Gogotsi",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7ta00149e",

language = "English (US)",

volume = "5",

pages = "5260--5265",

journal = "Journal of Materials Chemistry A",

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TY - JOUR

T1 - Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

AU - Chen, Chi

AU - Boota, Muhammad

AU - Xie, Xiuqiang

AU - Zhao, Mengqiang

AU - Anasori, Babak

AU - Ren, Chang E.

AU - Miao, Ling

AU - Jiang, Jianjun

AU - Gogotsi, Yury

PY - 2017

Y1 - 2017

N2 - In situ polymerization of 3,4-ethylenedioxythiophene (EDOT) is achieved on the surface of 2D Ti3C2Tx MXene without using any oxidant, resulting in improved lithium ion storage capability of Ti3C2Tx/poly-EDOT hybrids. A combined experimental and theoretical study revealed the mechanism of charge-transfer-induced polymerization of EDOT, which can be extended to other similar polymers.

AB - In situ polymerization of 3,4-ethylenedioxythiophene (EDOT) is achieved on the surface of 2D Ti3C2Tx MXene without using any oxidant, resulting in improved lithium ion storage capability of Ti3C2Tx/poly-EDOT hybrids. A combined experimental and theoretical study revealed the mechanism of charge-transfer-induced polymerization of EDOT, which can be extended to other similar polymers.

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U2 - 10.1039/c7ta00149e

DO - 10.1039/c7ta00149e

M3 - Article

AN - SCOPUS:85015333421

SN - 2050-7488

VL - 5

SP - 5260

EP - 5265

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 11

ER -

Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

Abstract

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