Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

Chi Chen; Muhammad Boota; Xiuqiang Xie; Mengqiang Zhao; Babak Anasori; Chang E. Ren; Ling Miao; Jianjun Jiang; Yury Gogotsi

doi:10.1039/c7ta00149e

Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

Chi Chen
, Muhammad Boota
, Xiuqiang Xie
, Mengqiang Zhao
, Babak Anasori
, Chang E. Ren
, Ling Miao
, Jianjun Jiang
, Yury Gogotsi

Research output: Contribution to journal › Article › peer-review

173 Scopus citations

Abstract

In situ polymerization of 3,4-ethylenedioxythiophene (EDOT) is achieved on the surface of 2D Ti₃C₂T_x MXene without using any oxidant, resulting in improved lithium ion storage capability of Ti₃C₂T_x/poly-EDOT hybrids. A combined experimental and theoretical study revealed the mechanism of charge-transfer-induced polymerization of EDOT, which can be extended to other similar polymers.

Original language	English (US)
Pages (from-to)	5260-5265
Number of pages	6
Journal	Journal of Materials Chemistry A
Volume	5
Issue number	11
DOIs	https://doi.org/10.1039/c7ta00149e
State	Published - 2017
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry
Renewable Energy, Sustainability and the Environment
General Materials Science

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10.1039/c7ta00149e

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title = "Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers",

abstract = "In situ polymerization of 3,4-ethylenedioxythiophene (EDOT) is achieved on the surface of 2D Ti3C2Tx MXene without using any oxidant, resulting in improved lithium ion storage capability of Ti3C2Tx/poly-EDOT hybrids. A combined experimental and theoretical study revealed the mechanism of charge-transfer-induced polymerization of EDOT, which can be extended to other similar polymers.",

author = "Chi Chen and Muhammad Boota and Xiuqiang Xie and Mengqiang Zhao and Babak Anasori and Ren, \{Chang E.\} and Ling Miao and Jianjun Jiang and Yury Gogotsi",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7ta00149e",

language = "English (US)",

volume = "5",

pages = "5260--5265",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

AU - Chen, Chi

AU - Boota, Muhammad

AU - Xie, Xiuqiang

AU - Zhao, Mengqiang

AU - Anasori, Babak

AU - Ren, Chang E.

AU - Miao, Ling

AU - Jiang, Jianjun

AU - Gogotsi, Yury

PY - 2017

Y1 - 2017

N2 - In situ polymerization of 3,4-ethylenedioxythiophene (EDOT) is achieved on the surface of 2D Ti3C2Tx MXene without using any oxidant, resulting in improved lithium ion storage capability of Ti3C2Tx/poly-EDOT hybrids. A combined experimental and theoretical study revealed the mechanism of charge-transfer-induced polymerization of EDOT, which can be extended to other similar polymers.

AB - In situ polymerization of 3,4-ethylenedioxythiophene (EDOT) is achieved on the surface of 2D Ti3C2Tx MXene without using any oxidant, resulting in improved lithium ion storage capability of Ti3C2Tx/poly-EDOT hybrids. A combined experimental and theoretical study revealed the mechanism of charge-transfer-induced polymerization of EDOT, which can be extended to other similar polymers.

UR - https://www.scopus.com/pages/publications/85015333421

UR - https://www.scopus.com/pages/publications/85015333421#tab=citedBy

U2 - 10.1039/c7ta00149e

DO - 10.1039/c7ta00149e

M3 - Article

AN - SCOPUS:85015333421

SN - 2050-7488

VL - 5

SP - 5260

EP - 5265

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 11

ER -

Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

Abstract

All Science Journal Classification (ASJC) codes

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