Chemiluminescence in the thermal decomposition of di(tert-butyl) trioxide

S. L. Khursan; V. V. Shereshovets; A. F. Khalizov; A. I. Voloshin; V. D. Komissarov; V. P. Kazakov

doi:10.1007/BF00698876

Chemiluminescence in the thermal decomposition of di(tert-butyl) trioxide

S. L. Khursan, V. V. Shereshovets, A. F. Khalizov, A. I. Voloshin, V. D. Komissarov, V. P. Kazakov

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Intense chemiluminescence (CL) in the visible and IR regions arising during the thermal decomposition of di(tert-butyl) trioxide has been observed. The decomposition rate constants have been determined. The emitter of CL in the IR region is singlet oxygen, that of CL in the visible region is triplet excited acetone. Kinetic and spectral data and thermochemical and MNDO calculations point to a homolytic mechanism of decomposition. The formation of the CL emitters occurs in the reactions of radicals that arise upon the decay of di(tert-butyl) trioxide.

Original language	English (US)
Pages (from-to)	1968-1971
Number of pages	4
Journal	Russian Chemical Bulletin
Volume	42
Issue number	12
DOIs	https://doi.org/10.1007/BF00698876
State	Published - Dec 1993
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry

Keywords

chemiluminescence, singlet oxygen
trioxides, mechanism of decomposition

Access to Document

10.1007/BF00698876

Cite this

@article{41eca6fa33a24c2d800aada970d6bacd,

title = "Chemiluminescence in the thermal decomposition of di(tert-butyl) trioxide",

abstract = "Intense chemiluminescence (CL) in the visible and IR regions arising during the thermal decomposition of di(tert-butyl) trioxide has been observed. The decomposition rate constants have been determined. The emitter of CL in the IR region is singlet oxygen, that of CL in the visible region is triplet excited acetone. Kinetic and spectral data and thermochemical and MNDO calculations point to a homolytic mechanism of decomposition. The formation of the CL emitters occurs in the reactions of radicals that arise upon the decay of di(tert-butyl) trioxide.",

keywords = "chemiluminescence, singlet oxygen, trioxides, mechanism of decomposition",

author = "Khursan, {S. L.} and Shereshovets, {V. V.} and Khalizov, {A. F.} and Voloshin, {A. I.} and Komissarov, {V. D.} and Kazakov, {V. P.}",

year = "1993",

month = dec,

doi = "10.1007/BF00698876",

language = "English (US)",

volume = "42",

pages = "1968--1971",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

number = "12",

}

TY - JOUR

T1 - Chemiluminescence in the thermal decomposition of di(tert-butyl) trioxide

AU - Khursan, S. L.

AU - Shereshovets, V. V.

AU - Khalizov, A. F.

AU - Voloshin, A. I.

AU - Komissarov, V. D.

AU - Kazakov, V. P.

PY - 1993/12

Y1 - 1993/12

N2 - Intense chemiluminescence (CL) in the visible and IR regions arising during the thermal decomposition of di(tert-butyl) trioxide has been observed. The decomposition rate constants have been determined. The emitter of CL in the IR region is singlet oxygen, that of CL in the visible region is triplet excited acetone. Kinetic and spectral data and thermochemical and MNDO calculations point to a homolytic mechanism of decomposition. The formation of the CL emitters occurs in the reactions of radicals that arise upon the decay of di(tert-butyl) trioxide.

AB - Intense chemiluminescence (CL) in the visible and IR regions arising during the thermal decomposition of di(tert-butyl) trioxide has been observed. The decomposition rate constants have been determined. The emitter of CL in the IR region is singlet oxygen, that of CL in the visible region is triplet excited acetone. Kinetic and spectral data and thermochemical and MNDO calculations point to a homolytic mechanism of decomposition. The formation of the CL emitters occurs in the reactions of radicals that arise upon the decay of di(tert-butyl) trioxide.

KW - chemiluminescence, singlet oxygen

KW - trioxides, mechanism of decomposition

UR - http://www.scopus.com/inward/record.url?scp=0039280268&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0039280268&partnerID=8YFLogxK

U2 - 10.1007/BF00698876

DO - 10.1007/BF00698876

M3 - Article

AN - SCOPUS:0039280268

SN - 1066-5285

VL - 42

SP - 1968

EP - 1971

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 12

ER -

Chemiluminescence in the thermal decomposition of di(tert-butyl) trioxide

Abstract

All Science Journal Classification (ASJC) codes

Keywords

Access to Document

Other files and links

Fingerprint

Cite this