Collision-induced dissociation studies of protonated ether - (H 2O)n (n = 1-3) clusters

Daniel J. Goebbert, Hao Chen, Paul G. Wenthold

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

We have studied the protonated ether - (H2O)n (n = 1-3) complexes containing tetrahydrofuran, dimethyl, diethyl, dibutyl, and butylmethyl ethers using a flowing afterglow triple-quadrupole mass spectrometer. Collision-induced dissociation, CID, of all clusters with n = 1,2 shows sequential water loss. The n = 3 cluster of dimethyl ether shows sequential water loss, while all other ether clusters display selective product formation. The CID spectra are interpreted based on known energetics, and theoretical studies of the dimethyl and diethyl ether systems.

Original languageEnglish (US)
Pages (from-to)242-247
Number of pages6
JournalJournal of Mass Spectrometry
Volume41
Issue number2
DOIs
StatePublished - Feb 1 2006
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Spectroscopy

Keywords

  • Collision-induced dissociation
  • Flowing afterglow mass spectrometry
  • Hydration
  • Ion solvation
  • Theoretical calculations

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