Comparison of K- and L3-edges of ClO3-: Evidence for mixed electronic and multiple scattering effects

Z. Y. Wu; Trevor A. Tyson; C. R. Natoli

doi:10.1016/0921-4526(94)00769-R

Comparison of K- and L₃-edges of ClO₃^-: Evidence for mixed electronic and multiple scattering effects

Z. Y. Wu
, Trevor A. Tyson
, C. R. Natoli

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

We present theoretical computations of the Cl K- and L_2,3-edges of KClO₃ and identify all prominent features in the experimental K-edge X-ray-absorption near-edge structure (XANES) spectrum. We have shown that some features are sensitive to the size of cluster used, and some low-energy structures in the experimental spectra cannot be explained as multiple scattering resonances and can possibly be attributed to vibronically coupled electronic transitions: 1s → nd or 1s → ε{lunate}d.

Original language	English (US)
Pages (from-to)	611-613
Number of pages	3
Journal	Physica B: Physics of Condensed Matter
Volume	208-209
Issue number	C
DOIs	https://doi.org/10.1016/0921-4526(94)00769-R
State	Published - Mar 1 1995
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering

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10.1016/0921-4526(94)00769-R

Cite this

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title = "Comparison of K- and L3-edges of ClO3-: Evidence for mixed electronic and multiple scattering effects",

abstract = "We present theoretical computations of the Cl K- and L2,3-edges of KClO3 and identify all prominent features in the experimental K-edge X-ray-absorption near-edge structure (XANES) spectrum. We have shown that some features are sensitive to the size of cluster used, and some low-energy structures in the experimental spectra cannot be explained as multiple scattering resonances and can possibly be attributed to vibronically coupled electronic transitions: 1s → nd or 1s → ε\{lunate\}d.",

author = "Wu, \{Z. Y.\} and Tyson, \{Trevor A.\} and Natoli, \{C. R.\}",

year = "1995",

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doi = "10.1016/0921-4526(94)00769-R",

language = "English (US)",

volume = "208-209",

pages = "611--613",

journal = "Physica B: Physics of Condensed Matter",

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publisher = "Elsevier B.V.",

number = "C",

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TY - JOUR

T1 - Comparison of K- and L3-edges of ClO3-

T2 - Evidence for mixed electronic and multiple scattering effects

AU - Wu, Z. Y.

AU - Tyson, Trevor A.

AU - Natoli, C. R.

PY - 1995/3/1

Y1 - 1995/3/1

N2 - We present theoretical computations of the Cl K- and L2,3-edges of KClO3 and identify all prominent features in the experimental K-edge X-ray-absorption near-edge structure (XANES) spectrum. We have shown that some features are sensitive to the size of cluster used, and some low-energy structures in the experimental spectra cannot be explained as multiple scattering resonances and can possibly be attributed to vibronically coupled electronic transitions: 1s → nd or 1s → ε{lunate}d.

AB - We present theoretical computations of the Cl K- and L2,3-edges of KClO3 and identify all prominent features in the experimental K-edge X-ray-absorption near-edge structure (XANES) spectrum. We have shown that some features are sensitive to the size of cluster used, and some low-energy structures in the experimental spectra cannot be explained as multiple scattering resonances and can possibly be attributed to vibronically coupled electronic transitions: 1s → nd or 1s → ε{lunate}d.

UR - https://www.scopus.com/pages/publications/0346555889

UR - https://www.scopus.com/pages/publications/0346555889#tab=citedBy

U2 - 10.1016/0921-4526(94)00769-R

DO - 10.1016/0921-4526(94)00769-R

M3 - Article

AN - SCOPUS:0346555889

SN - 0921-4526

VL - 208-209

SP - 611

EP - 613

JO - Physica B: Physics of Condensed Matter

JF - Physica B: Physics of Condensed Matter

IS - C

ER -

Comparison of K- and L₃-edges of ClO₃^-: Evidence for mixed electronic and multiple scattering effects

Abstract

All Science Journal Classification (ASJC) codes

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