Complex of chlorine dioxide with TEMPO and its conversion into oxoammonium salt

I. M. Ganiev; Q. K. Timerghazin; A. F. Khalizov; V. V. Shereshovets; A. I. Grigor'ev; G. A. Tolstikov

doi:10.1002/1099-1395(200101)14:1<38::AID-POC334>3.0.CO;2-Z

Complex of chlorine dioxide with TEMPO and its conversion into oxoammonium salt

I. M. Ganiev, Q. K. Timerghazin, A. F. Khalizov, V. V. Shereshovets, A. I. Grigor'ev, G. A. Tolstikov

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Complex formation between chlorine dioxide and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and its thermodynamic characteristics were studied in a number of organic solvents. The complex was shown to transform into the oxoammonium salt. The kinetics of this reaction were studied, and the equilibrium constants of the TEMPO-ClO₂ complex, determined by direct measurements and from kinetic data, were found to be in good agreement. The electronic structure of the complex is discussed in the light of recent theoretical results.

Original language	English (US)
Pages (from-to)	38-42
Number of pages	5
Journal	Journal of Physical Organic Chemistry
Volume	14
Issue number	1
DOIs	https://doi.org/10.1002/1099-1395(200101)14:1<38::AID-POC334>3.0.CO;2-Z
State	Published - Jan 2001
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry

Keywords

Chlorine dioxide
Complexes
Nitroxyl radicals
Oxoammonium salts

Access to Document

10.1002/1099-1395(200101)14:1<38::AID-POC334>3.0.CO;2-Z

Cite this

@article{40d779c26828409c99a04d49edbb3d1c,

title = "Complex of chlorine dioxide with TEMPO and its conversion into oxoammonium salt",

abstract = "Complex formation between chlorine dioxide and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and its thermodynamic characteristics were studied in a number of organic solvents. The complex was shown to transform into the oxoammonium salt. The kinetics of this reaction were studied, and the equilibrium constants of the TEMPO-ClO2 complex, determined by direct measurements and from kinetic data, were found to be in good agreement. The electronic structure of the complex is discussed in the light of recent theoretical results.",

keywords = "Chlorine dioxide, Complexes, Nitroxyl radicals, Oxoammonium salts",

author = "Ganiev, {I. M.} and Timerghazin, {Q. K.} and Khalizov, {A. F.} and Shereshovets, {V. V.} and Grigor'ev, {A. I.} and Tolstikov, {G. A.}",

year = "2001",

month = jan,

doi = "10.1002/1099-1395(200101)14:1<38::AID-POC334>3.0.CO;2-Z",

language = "English (US)",

volume = "14",

pages = "38--42",

journal = "Journal of Physical Organic Chemistry",

issn = "0894-3230",

publisher = "John Wiley and Sons Ltd",

number = "1",

}

TY - JOUR

T1 - Complex of chlorine dioxide with TEMPO and its conversion into oxoammonium salt

AU - Ganiev, I. M.

AU - Timerghazin, Q. K.

AU - Khalizov, A. F.

AU - Shereshovets, V. V.

AU - Grigor'ev, A. I.

AU - Tolstikov, G. A.

PY - 2001/1

Y1 - 2001/1

N2 - Complex formation between chlorine dioxide and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and its thermodynamic characteristics were studied in a number of organic solvents. The complex was shown to transform into the oxoammonium salt. The kinetics of this reaction were studied, and the equilibrium constants of the TEMPO-ClO2 complex, determined by direct measurements and from kinetic data, were found to be in good agreement. The electronic structure of the complex is discussed in the light of recent theoretical results.

AB - Complex formation between chlorine dioxide and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and its thermodynamic characteristics were studied in a number of organic solvents. The complex was shown to transform into the oxoammonium salt. The kinetics of this reaction were studied, and the equilibrium constants of the TEMPO-ClO2 complex, determined by direct measurements and from kinetic data, were found to be in good agreement. The electronic structure of the complex is discussed in the light of recent theoretical results.

KW - Chlorine dioxide

KW - Complexes

KW - Nitroxyl radicals

KW - Oxoammonium salts

UR - http://www.scopus.com/inward/record.url?scp=0002855387&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0002855387&partnerID=8YFLogxK

U2 - 10.1002/1099-1395(200101)14:1<38::AID-POC334>3.0.CO;2-Z

DO - 10.1002/1099-1395(200101)14:1<38::AID-POC334>3.0.CO;2-Z

M3 - Article

AN - SCOPUS:0002855387

SN - 0894-3230

VL - 14

SP - 38

EP - 42

JO - Journal of Physical Organic Chemistry

JF - Journal of Physical Organic Chemistry

IS - 1

ER -

Complex of chlorine dioxide with TEMPO and its conversion into oxoammonium salt

Abstract

All Science Journal Classification (ASJC) codes

Keywords

Access to Document

Other files and links

Fingerprint

Cite this