Complexes of chlorine dioxide with nitroxyl radicals

Ilgiz M. Ganiev, Qadir K. Timerghazin, Alexey F. Khalizov, Nadezhda M. Andriyashina, Valerii V. Shereshovets, Leonid B. Volodarsky, Genrikh A. Tolstikov

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

Chlorine dioxide forms red-colored (λ(max)=480 nm) CT complexes with persistent piperidine and imidazoline nitroxyl radicals in diethyl ether, n- pentane, carbon tetrachloride, methylene chloride and on silica gel surface. Equilibrium constants, enthalpy and entropy of formation and extinction coefficient of the complex between ClO2 and 2,2.6,6-tetramethyl-4- oxypiperidin-1-oxyl 1 in diethyl ether were deter- mined. In Et2O the complex is stable under normal conditions, in other media it transforms into the oxoammonium salt.

Original languageEnglish (US)
Pages (from-to)4737-4740
Number of pages4
JournalTetrahedron Letters
Volume40
Issue number25
DOIs
StatePublished - Jun 18 1999
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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