Cyclopropylcarbinyl-to-Homoallyl Carbocation Equilibria Influence the Stereospecificity in the Nucleophilic Substitution of Cyclopropylcarbinols

Keyphrases

• Nucleophilic Attack 100%
• Phenyl 100%
• Stereospecificity 100%
• Carbocations 100%
• Nucleophilic Substitution 100%
• Cyclopropylcarbinol 100%
• High Energy 50%
• Halides 50%
• Reaction Mechanism 50%
• Computational Investigation 50%
• Activation Barrier 50%
• Transition Structure 50%
• Energy Transition 50%
• Ring Opening 50%
• Stable Intermediate 50%
• Stereospecific 50%
• DLPNO-CCSD(T) 50%
• Diastereomers 50%
• Trichloroacetimidate 50%
• D Optimization 50%
• Stereospecific Reactions 50%
• Carbocation Intermediates 50%

Chemistry

• Cation 100%
• Carbocation 100%
• Nucleophilic Substitution 100%
• Halide 20%
• CCSD 20%
• Ring Opening Reaction 20%
• Trichloroacetate 20%
• Diastereomer 20%