Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba3(ZnB5O10)PO4

Hongwei Yu; Weiguo Zhang; Joshua Young; James M. Rondinelli; P. Shiv Halasyamani

doi:10.1002/adma.201503951

Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba₃(ZnB₅O₁₀)PO₄

Hongwei Yu, Weiguo Zhang, Joshua Young, James M. Rondinelli, P. Shiv Halasyamani

Research output: Contribution to journal › Article › peer-review

265 Scopus citations

Abstract

Access to the elusive deep-ultraviolet by direct second harmonic generation (SHG) enabled by a new beryllium-free zincoborate-phosphate crystal is reported. Ba₃(ZnB₅O₁₀)PO₄, exhibits large SHG responses at 1064 and 532 nm and a short 180 nm absorption edge. Centimeter-size crystals are grown, and quantum mechanical calculations demonstrate the key role played by ZnO₄ tetrahedra in the enhanced optical responses.

Original language	English (US)
Pages (from-to)	7380-7385
Number of pages	6
Journal	Advanced Materials
Volume	27
Issue number	45
DOIs	https://doi.org/10.1002/adma.201503951
State	Published - Dec 2 2015
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Materials Science
Mechanics of Materials
Mechanical Engineering

Keywords

DFT calculations
borate-phosphates
deep ultraviolet
nonlinear optical materials
second-harmonic generation

Access to Document

10.1002/adma.201503951

Cite this

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title = "Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba3(ZnB5O10)PO4",

abstract = "Access to the elusive deep-ultraviolet by direct second harmonic generation (SHG) enabled by a new beryllium-free zincoborate-phosphate crystal is reported. Ba3(ZnB5O10)PO4, exhibits large SHG responses at 1064 and 532 nm and a short 180 nm absorption edge. Centimeter-size crystals are grown, and quantum mechanical calculations demonstrate the key role played by ZnO4 tetrahedra in the enhanced optical responses.",

keywords = "DFT calculations, borate-phosphates, deep ultraviolet, nonlinear optical materials, second-harmonic generation",

author = "Hongwei Yu and Weiguo Zhang and Joshua Young and Rondinelli, \{James M.\} and Halasyamani, \{P. Shiv\}",

note = "Publisher Copyright: {\textcopyright} 2015 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

year = "2015",

month = dec,

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doi = "10.1002/adma.201503951",

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journal = "Advanced Materials",

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T1 - Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba3(ZnB5O10)PO4

AU - Yu, Hongwei

AU - Zhang, Weiguo

AU - Young, Joshua

AU - Rondinelli, James M.

AU - Halasyamani, P. Shiv

PY - 2015/12/2

Y1 - 2015/12/2

N2 - Access to the elusive deep-ultraviolet by direct second harmonic generation (SHG) enabled by a new beryllium-free zincoborate-phosphate crystal is reported. Ba3(ZnB5O10)PO4, exhibits large SHG responses at 1064 and 532 nm and a short 180 nm absorption edge. Centimeter-size crystals are grown, and quantum mechanical calculations demonstrate the key role played by ZnO4 tetrahedra in the enhanced optical responses.

AB - Access to the elusive deep-ultraviolet by direct second harmonic generation (SHG) enabled by a new beryllium-free zincoborate-phosphate crystal is reported. Ba3(ZnB5O10)PO4, exhibits large SHG responses at 1064 and 532 nm and a short 180 nm absorption edge. Centimeter-size crystals are grown, and quantum mechanical calculations demonstrate the key role played by ZnO4 tetrahedra in the enhanced optical responses.

KW - DFT calculations

KW - borate-phosphates

KW - deep ultraviolet

KW - nonlinear optical materials

KW - second-harmonic generation

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