Development of High-Capacity Periodate Battery with Three-Dimensional-Printed Casing Accommodating Replaceable Flexible Electrodes

Zhiqian Wang; Xianyang Meng; Kun Chen; Somenath Mitra

doi:10.1021/acsami.8b05578

Development of High-Capacity Periodate Battery with Three-Dimensional-Printed Casing Accommodating Replaceable Flexible Electrodes

Zhiqian Wang, Xianyang Meng, Kun Chen, Somenath Mitra

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

We present the development of a novel battery comprising iron(III) periodate complex cathode and zinc anode. The periodate complex [H₇Fe₄(IO₄)₃O₈] was prepared by a precipitation reaction between Fe(NO₃)₃ and NaIO₄ and was used in battery development for the first time. The periodate complex along with 14% carbon nanotubes and a polytetrafluoroethylene coating formed a stable flexible electrode, and the battery showed specific capacity as high as 300 mA h g^-1. Compared to single-electron processes in conventional cathode reactions, the possibility to significantly enhancing the cathode specific capacity via a multielectron process associated with valence change from I(VII) to I₂ is demonstrated. A novel three-dimensional printed reserve battery design comprising replaceable electrodes and acetic acid electrolyte is also presented.

Original language	English (US)
Pages (from-to)	30257-30264
Number of pages	8
Journal	ACS Applied Materials and Interfaces
Volume	10
Issue number	36
DOIs	https://doi.org/10.1021/acsami.8b05578
State	Published - Sep 12 2018

All Science Journal Classification (ASJC) codes

General Materials Science

Keywords

3D printing
carbon nanotube
flexible electrode
periodate
reserve battery

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10.1021/acsami.8b05578

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title = "Development of High-Capacity Periodate Battery with Three-Dimensional-Printed Casing Accommodating Replaceable Flexible Electrodes",

abstract = "We present the development of a novel battery comprising iron(III) periodate complex cathode and zinc anode. The periodate complex [H7Fe4(IO4)3O8] was prepared by a precipitation reaction between Fe(NO3)3 and NaIO4 and was used in battery development for the first time. The periodate complex along with 14% carbon nanotubes and a polytetrafluoroethylene coating formed a stable flexible electrode, and the battery showed specific capacity as high as 300 mA h g-1. Compared to single-electron processes in conventional cathode reactions, the possibility to significantly enhancing the cathode specific capacity via a multielectron process associated with valence change from I(VII) to I2 is demonstrated. A novel three-dimensional printed reserve battery design comprising replaceable electrodes and acetic acid electrolyte is also presented.",

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AU - Mitra, Somenath

PY - 2018/9/12

Y1 - 2018/9/12

N2 - We present the development of a novel battery comprising iron(III) periodate complex cathode and zinc anode. The periodate complex [H7Fe4(IO4)3O8] was prepared by a precipitation reaction between Fe(NO3)3 and NaIO4 and was used in battery development for the first time. The periodate complex along with 14% carbon nanotubes and a polytetrafluoroethylene coating formed a stable flexible electrode, and the battery showed specific capacity as high as 300 mA h g-1. Compared to single-electron processes in conventional cathode reactions, the possibility to significantly enhancing the cathode specific capacity via a multielectron process associated with valence change from I(VII) to I2 is demonstrated. A novel three-dimensional printed reserve battery design comprising replaceable electrodes and acetic acid electrolyte is also presented.

AB - We present the development of a novel battery comprising iron(III) periodate complex cathode and zinc anode. The periodate complex [H7Fe4(IO4)3O8] was prepared by a precipitation reaction between Fe(NO3)3 and NaIO4 and was used in battery development for the first time. The periodate complex along with 14% carbon nanotubes and a polytetrafluoroethylene coating formed a stable flexible electrode, and the battery showed specific capacity as high as 300 mA h g-1. Compared to single-electron processes in conventional cathode reactions, the possibility to significantly enhancing the cathode specific capacity via a multielectron process associated with valence change from I(VII) to I2 is demonstrated. A novel three-dimensional printed reserve battery design comprising replaceable electrodes and acetic acid electrolyte is also presented.

KW - 3D printing

KW - carbon nanotube

KW - flexible electrode

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KW - reserve battery

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Development of High-Capacity Periodate Battery with Three-Dimensional-Printed Casing Accommodating Replaceable Flexible Electrodes

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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