Abstract
We studied temperature-dependent high-resolution optical spectra of Er 3+ probe ion introduced into single crystals of the borates RFe 3(BO3)4, R=Gd, Tb, Er, and Y. Exchange splittings of the Er3+ Kramers doublets were found from the spectra. They manifest the magnetic ordering in Gd, Tb, Er, and Y iron borates at 37, 41, 38, and 39 K, respectively, and a spin-reorientation in GdFe 3(BO3)4: Er (1%) at TR=7.5 K. From a comparison of the data on Y, Er, and Tb iron borates with those on GdFe 3(BO3)4 where the magnetic structure has been determined earlier, we suggest the following patterns of the ordered Fe magnetic moments: mFe⊥c for R=Er and Y; mFe|c for R=Tb.
| Original language | English (US) |
|---|---|
| Pages (from-to) | e440-e443 |
| Journal | Journal of Magnetism and Magnetic Materials |
| Volume | 300 |
| Issue number | 1 |
| DOIs | |
| State | Published - May 2006 |
| Externally published | Yes |
| Event | Third International Symposium on Magnetism 2005 - Duration: Jun 26 2005 → Jun 30 2005 |
All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics
Keywords
- Magnetic ordering
- Optical spectroscopy
- Rare-earth iron borates
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