TY - JOUR
T1 - Dynamic covalent and noncovalent assembly of o-nitrosocumene in organic solvents and water
AU - Rogers, Cory H.
AU - Pradeep, Anu
AU - Galiano, Layla A.
AU - Kelley, S. Ariel
AU - Varadharajan, Ramkumar
AU - Belmore, Ken
AU - Whitt, Logan M.
AU - Li, Yanmei
AU - Champagne, Pier Alexandre
AU - Ramamurthy, Vaidhyanathan
AU - Blackstock, Silas C.
N1 - Publisher Copyright:
© 2024 The Royal Society of Chemistry.
PY - 2024/11/5
Y1 - 2024/11/5
N2 - ortho-Nitrosocumene (o-NC) exhibits dynamic N,N bonding, interchanging monomer and E/Z-azodioxide dimer structures, the extent of which depends on the environment. As a solid, o-NC is a Z-dimer; in organic solvent, the monomer is favored; and in water, dimers are favored. A supramolecular assembly of o-NC is observed as a separate species by NMR in water, shown to be a novel nanometer-sized aggregate containing ~2000 molecules.
AB - ortho-Nitrosocumene (o-NC) exhibits dynamic N,N bonding, interchanging monomer and E/Z-azodioxide dimer structures, the extent of which depends on the environment. As a solid, o-NC is a Z-dimer; in organic solvent, the monomer is favored; and in water, dimers are favored. A supramolecular assembly of o-NC is observed as a separate species by NMR in water, shown to be a novel nanometer-sized aggregate containing ~2000 molecules.
UR - https://www.scopus.com/pages/publications/85209125210
UR - https://www.scopus.com/pages/publications/85209125210#tab=citedBy
U2 - 10.1039/d4cc03955f
DO - 10.1039/d4cc03955f
M3 - Article
C2 - 39499547
AN - SCOPUS:85209125210
SN - 1359-7345
VL - 60
SP - 13899
EP - 13902
JO - Chemical Communications
JF - Chemical Communications
IS - 94
ER -