Dynamic covalent and noncovalent assembly of o-nitrosocumene in organic solvents and water

Cory H. Rogers; Anu Pradeep; Layla A. Galiano; S. Ariel Kelley; Ramkumar Varadharajan; Ken Belmore; Logan M. Whitt; Yanmei Li; Pier Alexandre Champagne; Vaidhyanathan Ramamurthy; Silas C. Blackstock

doi:10.1039/d4cc03955f

Dynamic covalent and noncovalent assembly of o-nitrosocumene in organic solvents and water

Cory H. Rogers
, Anu Pradeep
, Layla A. Galiano
, S. Ariel Kelley
, Ramkumar Varadharajan
, Ken Belmore
, Logan M. Whitt
, Yanmei Li
, Pier Alexandre Champagne
, Vaidhyanathan Ramamurthy
, Silas C. Blackstock

Chemistry and Environmental Science

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

ortho-Nitrosocumene (o-NC) exhibits dynamic N,N bonding, interchanging monomer and E/Z-azodioxide dimer structures, the extent of which depends on the environment. As a solid, o-NC is a Z-dimer; in organic solvent, the monomer is favored; and in water, dimers are favored. A supramolecular assembly of o-NC is observed as a separate species by NMR in water, shown to be a novel nanometer-sized aggregate containing ~2000 molecules.

Original language	English (US)
Pages (from-to)	13899-13902
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	94
DOIs	https://doi.org/10.1039/d4cc03955f
State	Published - Nov 5 2024

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d4cc03955f

Cite this

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title = "Dynamic covalent and noncovalent assembly of o-nitrosocumene in organic solvents and water",

abstract = "ortho-Nitrosocumene (o-NC) exhibits dynamic N,N bonding, interchanging monomer and E/Z-azodioxide dimer structures, the extent of which depends on the environment. As a solid, o-NC is a Z-dimer; in organic solvent, the monomer is favored; and in water, dimers are favored. A supramolecular assembly of o-NC is observed as a separate species by NMR in water, shown to be a novel nanometer-sized aggregate containing \textasciitilde{}2000 molecules.",

author = "Rogers, \{Cory H.\} and Anu Pradeep and Galiano, \{Layla A.\} and Kelley, \{S. Ariel\} and Ramkumar Varadharajan and Ken Belmore and Whitt, \{Logan M.\} and Yanmei Li and Champagne, \{Pier Alexandre\} and Vaidhyanathan Ramamurthy and Blackstock, \{Silas C.\}",

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doi = "10.1039/d4cc03955f",

language = "English (US)",

volume = "60",

pages = "13899--13902",

journal = "Chemical Communications",

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TY - JOUR

T1 - Dynamic covalent and noncovalent assembly of o-nitrosocumene in organic solvents and water

AU - Rogers, Cory H.

AU - Pradeep, Anu

AU - Galiano, Layla A.

AU - Kelley, S. Ariel

AU - Varadharajan, Ramkumar

AU - Belmore, Ken

AU - Whitt, Logan M.

AU - Li, Yanmei

AU - Champagne, Pier Alexandre

AU - Ramamurthy, Vaidhyanathan

AU - Blackstock, Silas C.

PY - 2024/11/5

Y1 - 2024/11/5

N2 - ortho-Nitrosocumene (o-NC) exhibits dynamic N,N bonding, interchanging monomer and E/Z-azodioxide dimer structures, the extent of which depends on the environment. As a solid, o-NC is a Z-dimer; in organic solvent, the monomer is favored; and in water, dimers are favored. A supramolecular assembly of o-NC is observed as a separate species by NMR in water, shown to be a novel nanometer-sized aggregate containing ~2000 molecules.

AB - ortho-Nitrosocumene (o-NC) exhibits dynamic N,N bonding, interchanging monomer and E/Z-azodioxide dimer structures, the extent of which depends on the environment. As a solid, o-NC is a Z-dimer; in organic solvent, the monomer is favored; and in water, dimers are favored. A supramolecular assembly of o-NC is observed as a separate species by NMR in water, shown to be a novel nanometer-sized aggregate containing ~2000 molecules.

UR - https://www.scopus.com/pages/publications/85209125210

UR - https://www.scopus.com/pages/publications/85209125210#tab=citedBy

U2 - 10.1039/d4cc03955f

DO - 10.1039/d4cc03955f

M3 - Article

C2 - 39499547

AN - SCOPUS:85209125210

SN - 1359-7345

VL - 60

SP - 13899

EP - 13902

JO - Chemical Communications

JF - Chemical Communications

IS - 94

ER -

Dynamic covalent and noncovalent assembly of o-nitrosocumene in organic solvents and water

Abstract

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