Dynamic shear modulus of tricresyl phosphate and squalane

Robert D. Deegan, Robert L. Leheny, Narayanan Menon, Sidney R. Nagel, David C. Venerus

Research output: Contribution to journalArticlepeer-review

57 Scopus citations

Abstract

We have measured the shear modulus and viscosity of two supercooled liquids: tricresyl phosphate and squalane. In both cases we find that the width of the peak in the imaginary part of the shear modulus narrows as the temperature is lowered toward the glass transition temperature. For tricresyl phosphate, we find no evidence for a decoupling of the viscosity and shear modulus relaxation times from the relaxation times determined by dielectric spectroscopy.

Original languageEnglish (US)
Pages (from-to)4066-4070
Number of pages5
JournalJournal of Physical Chemistry B
Volume103
Issue number20
DOIs
StatePublished - May 20 1999
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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