Effect of medium on the rate constant of decomposition of di(tert-butyl)trioxide

A. F. Khalizov, S. L. Khursan, V. V. Shereshovets

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

It was found that the medium affects the rate constant of the thermal decomposition of di(tert-butyl)trioxide. In all solvents studied, the decomposition occurred according to the first-order law. The effect of the solvent on the rate constant was analyzed within the framework of the Koppel-Palm equation.

Original languageEnglish (US)
Pages (from-to)1127-1128
Number of pages2
JournalRussian Chemical Bulletin
Volume44
Issue number6
DOIs
StatePublished - Jun 1995
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Keywords

  • chemiluminescence
  • decomposition mechanism.
  • trioxide

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