Effect of medium on the rate constant of decomposition of di(tert-butyl)trioxide

A. F. Khalizov; S. L. Khursan; V. V. Shereshovets

doi:10.1007/BF00707068

Effect of medium on the rate constant of decomposition of di(tert-butyl)trioxide

A. F. Khalizov, S. L. Khursan, V. V. Shereshovets

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

It was found that the medium affects the rate constant of the thermal decomposition of di(tert-butyl)trioxide. In all solvents studied, the decomposition occurred according to the first-order law. The effect of the solvent on the rate constant was analyzed within the framework of the Koppel-Palm equation.

Original language	English (US)
Pages (from-to)	1127-1128
Number of pages	2
Journal	Russian Chemical Bulletin
Volume	44
Issue number	6
DOIs	https://doi.org/10.1007/BF00707068
State	Published - Jun 1995
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry

Keywords

chemiluminescence
decomposition mechanism.
trioxide

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10.1007/BF00707068

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title = "Effect of medium on the rate constant of decomposition of di(tert-butyl)trioxide",

abstract = "It was found that the medium affects the rate constant of the thermal decomposition of di(tert-butyl)trioxide. In all solvents studied, the decomposition occurred according to the first-order law. The effect of the solvent on the rate constant was analyzed within the framework of the Koppel-Palm equation.",

keywords = "chemiluminescence, decomposition mechanism., trioxide",

author = "Khalizov, {A. F.} and Khursan, {S. L.} and Shereshovets, {V. V.}",

year = "1995",

month = jun,

doi = "10.1007/BF00707068",

language = "English (US)",

volume = "44",

pages = "1127--1128",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

number = "6",

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T1 - Effect of medium on the rate constant of decomposition of di(tert-butyl)trioxide

AU - Khalizov, A. F.

AU - Khursan, S. L.

AU - Shereshovets, V. V.

PY - 1995/6

Y1 - 1995/6

N2 - It was found that the medium affects the rate constant of the thermal decomposition of di(tert-butyl)trioxide. In all solvents studied, the decomposition occurred according to the first-order law. The effect of the solvent on the rate constant was analyzed within the framework of the Koppel-Palm equation.

AB - It was found that the medium affects the rate constant of the thermal decomposition of di(tert-butyl)trioxide. In all solvents studied, the decomposition occurred according to the first-order law. The effect of the solvent on the rate constant was analyzed within the framework of the Koppel-Palm equation.

KW - chemiluminescence

KW - decomposition mechanism.

KW - trioxide

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UR - http://www.scopus.com/inward/citedby.url?scp=0041059126&partnerID=8YFLogxK

U2 - 10.1007/BF00707068

DO - 10.1007/BF00707068

M3 - Article

AN - SCOPUS:0041059126

SN - 1066-5285

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SP - 1127

EP - 1128

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 6

ER -

Effect of medium on the rate constant of decomposition of di(tert-butyl)trioxide

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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