Effect of the medium on the decomposition rate of di-t-butyl trioxide

A. F. Khalizov; O. N. Makarova; S. L. Khursan; V. V. Shereshovets

doi:10.1007/bf02071036

Effect of the medium on the decomposition rate of di-t-butyl trioxide

A. F. Khalizov, O. N. Makarova, S. L. Khursan, V. V. Shereshovets

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Using the chemiluminescence method, the effect of the medium on the overall rate constant of the thermal decomposition of di-tert-butyl trioxide has been studied. In all solvents investigated the decomposition occurs in accordance with a first order rate law. The effect of solvent on the rate constant (0 °C) is analyzed.

Original language	English (US)
Pages (from-to)	427-430
Number of pages	4
Journal	Reaction Kinetics and Catalysis Letters
Volume	54
Issue number	2
DOIs	https://doi.org/10.1007/bf02071036
State	Published - Feb 1995
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Physical and Theoretical Chemistry

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10.1007/bf02071036

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title = "Effect of the medium on the decomposition rate of di-t-butyl trioxide",

abstract = "Using the chemiluminescence method, the effect of the medium on the overall rate constant of the thermal decomposition of di-tert-butyl trioxide has been studied. In all solvents investigated the decomposition occurs in accordance with a first order rate law. The effect of solvent on the rate constant (0 °C) is analyzed.",

author = "Khalizov, {A. F.} and Makarova, {O. N.} and Khursan, {S. L.} and Shereshovets, {V. V.}",

year = "1995",

month = feb,

doi = "10.1007/bf02071036",

language = "English (US)",

volume = "54",

pages = "427--430",

journal = "Reaction Kinetics and Catalysis Letters",

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publisher = "Springer Science and Business Media B.V.",

number = "2",

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T1 - Effect of the medium on the decomposition rate of di-t-butyl trioxide

AU - Khalizov, A. F.

AU - Makarova, O. N.

AU - Khursan, S. L.

AU - Shereshovets, V. V.

PY - 1995/2

Y1 - 1995/2

N2 - Using the chemiluminescence method, the effect of the medium on the overall rate constant of the thermal decomposition of di-tert-butyl trioxide has been studied. In all solvents investigated the decomposition occurs in accordance with a first order rate law. The effect of solvent on the rate constant (0 °C) is analyzed.

AB - Using the chemiluminescence method, the effect of the medium on the overall rate constant of the thermal decomposition of di-tert-butyl trioxide has been studied. In all solvents investigated the decomposition occurs in accordance with a first order rate law. The effect of solvent on the rate constant (0 °C) is analyzed.

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U2 - 10.1007/bf02071036

DO - 10.1007/bf02071036

M3 - Article

AN - SCOPUS:0142161572

SN - 0133-1736

VL - 54

SP - 427

EP - 430

JO - Reaction Kinetics and Catalysis Letters

JF - Reaction Kinetics and Catalysis Letters

IS - 2

ER -

Effect of the medium on the decomposition rate of di-t-butyl trioxide

Abstract

All Science Journal Classification (ASJC) codes

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