EPR study of the reaction of C60 with chlorine dioxide: Experimental evidence for the formation of the C60 radical cation

Vyacheslav I. Sokolov; Vasily V. Bashilov; Qadir K. Timerghazin; Elena V. Avzyanova; Alexey F. Khalizov; Nikolay M. Shishlov; Valery V. Shereshovets

doi:10.1070/mc1999v009n02abeh001046

EPR study of the reaction of C₆₀ with chlorine dioxide: Experimental evidence for the formation of the C₆₀ radical cation

Vyacheslav I. Sokolov, Vasily V. Bashilov, Qadir K. Timerghazin, Elena V. Avzyanova, Alexey F. Khalizov, Nikolay M. Shishlov, Valery V. Shereshovets

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Abstract

The interaction of chlorine dioxide with fullerene C₆₀ affords a brown precipitate, and its EPR spectrum exhibits an asymmetric singlet signal (g = 2.0029, ΔH_pp = 0.2 mT) tentatively assigned to the fullerene radical cation.

Original language	English (US)
Pages (from-to)	XVII-XVIII
Journal	Mendeleev Communications
Volume	9
Issue number	2
DOIs	https://doi.org/10.1070/mc1999v009n02abeh001046
State	Published - 1999
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry

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10.1070/mc1999v009n02abeh001046

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title = "EPR study of the reaction of C60 with chlorine dioxide: Experimental evidence for the formation of the C60 radical cation",

abstract = "The interaction of chlorine dioxide with fullerene C60 affords a brown precipitate, and its EPR spectrum exhibits an asymmetric singlet signal (g = 2.0029, ΔHpp = 0.2 mT) tentatively assigned to the fullerene radical cation.",

author = "Sokolov, {Vyacheslav I.} and Bashilov, {Vasily V.} and Timerghazin, {Qadir K.} and Avzyanova, {Elena V.} and Khalizov, {Alexey F.} and Shishlov, {Nikolay M.} and Shereshovets, {Valery V.}",

year = "1999",

doi = "10.1070/mc1999v009n02abeh001046",

language = "English (US)",

volume = "9",

pages = "XVII--XVIII",

journal = "Mendeleev Communications",

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T1 - EPR study of the reaction of C60 with chlorine dioxide

T2 - Experimental evidence for the formation of the C60 radical cation

AU - Sokolov, Vyacheslav I.

AU - Bashilov, Vasily V.

AU - Timerghazin, Qadir K.

AU - Avzyanova, Elena V.

AU - Khalizov, Alexey F.

AU - Shishlov, Nikolay M.

AU - Shereshovets, Valery V.

PY - 1999

Y1 - 1999

N2 - The interaction of chlorine dioxide with fullerene C60 affords a brown precipitate, and its EPR spectrum exhibits an asymmetric singlet signal (g = 2.0029, ΔHpp = 0.2 mT) tentatively assigned to the fullerene radical cation.

AB - The interaction of chlorine dioxide with fullerene C60 affords a brown precipitate, and its EPR spectrum exhibits an asymmetric singlet signal (g = 2.0029, ΔHpp = 0.2 mT) tentatively assigned to the fullerene radical cation.

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U2 - 10.1070/mc1999v009n02abeh001046

DO - 10.1070/mc1999v009n02abeh001046

M3 - Article

AN - SCOPUS:0039253371

SN - 0959-9436

VL - 9

SP - XVII-XVIII

JO - Mendeleev Communications

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ER -

EPR study of the reaction of C₆₀ with chlorine dioxide: Experimental evidence for the formation of the C₆₀ radical cation

Abstract

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