EPR study of the reaction of C60 with chlorine dioxide: Experimental evidence for the formation of the C60 radical cation

Vyacheslav I. Sokolov, Vasily V. Bashilov, Qadir K. Timerghazin, Elena V. Avzyanova, Alexey F. Khalizov, Nikolay M. Shishlov, Valery V. Shereshovets

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Abstract

The interaction of chlorine dioxide with fullerene C60 affords a brown precipitate, and its EPR spectrum exhibits an asymmetric singlet signal (g = 2.0029, ΔHpp = 0.2 mT) tentatively assigned to the fullerene radical cation.

Original languageEnglish (US)
Pages (from-to)XVII-XVIII
JournalMendeleev Communications
Volume9
Issue number2
DOIs
StatePublished - 1999
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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