EPR study of the reaction of C60 with chlorine dioxide: Experimental evidence for the formation of the C60 radical cation

  • Vyacheslav I. Sokolov
  • , Vasily V. Bashilov
  • , Qadir K. Timerghazin
  • , Elena V. Avzyanova
  • , Alexey F. Khalizov
  • , Nikolay M. Shishlov
  • , Valery V. Shereshovets

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

The interaction of chlorine dioxide with fullerene C60 affords a brown precipitate, and its EPR spectrum exhibits an asymmetric singlet signal (g = 2.0029, ΔHpp = 0.2 mT) tentatively assigned to the fullerene radical cation.

Original languageEnglish (US)
Pages (from-to)XVII-XVIII
JournalMendeleev Communications
Volume9
Issue number2
DOIs
StatePublished - 1999
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General Chemistry

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