ESR studies of radical breakdown for di-t-butyl trioxide

S. L. Khursan, V. V. Shereshovets, N. M. Shishlov, A. F. Khalizov, V. D. Komissarov

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

ESR data show thermal breakdown of the title trioxide into peroxy and alkoxy radicals ROO. and RO., respectively. Equilibrium constants were calculated for the formation of tetroxide ROOOOR from two peroxy radicals. Their thermodynamic parameters were determined at temperatures ranging within 193-173 K.

Original languageEnglish (US)
Pages (from-to)249-254
Number of pages6
JournalReaction Kinetics & Catalysis Letters
Volume52
Issue number2
DOIs
StatePublished - Jun 1 1994
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Physical and Theoretical Chemistry

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