ESR studies of radical breakdown for di-t-butyl trioxide

S. L. Khursan; V. V. Shereshovets; N. M. Shishlov; A. F. Khalizov; V. D. Komissarov

doi:10.1007/BF02067795

ESR studies of radical breakdown for di-t-butyl trioxide

S. L. Khursan, V. V. Shereshovets, N. M. Shishlov, A. F. Khalizov, V. D. Komissarov

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Abstract

ESR data show thermal breakdown of the title trioxide into peroxy and alkoxy radicals ROO^. and RO^., respectively. Equilibrium constants were calculated for the formation of tetroxide ROOOOR from two peroxy radicals. Their thermodynamic parameters were determined at temperatures ranging within 193-173 K.

Original language	English (US)
Pages (from-to)	249-254
Number of pages	6
Journal	Reaction Kinetics & Catalysis Letters
Volume	52
Issue number	2
DOIs	https://doi.org/10.1007/BF02067795
State	Published - Jun 1994
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Physical and Theoretical Chemistry

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10.1007/BF02067795

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@article{17c50ac8d51f4afd8df33e6b013ddd98,

title = "ESR studies of radical breakdown for di-t-butyl trioxide",

abstract = "ESR data show thermal breakdown of the title trioxide into peroxy and alkoxy radicals ROO. and RO., respectively. Equilibrium constants were calculated for the formation of tetroxide ROOOOR from two peroxy radicals. Their thermodynamic parameters were determined at temperatures ranging within 193-173 K.",

author = "Khursan, {S. L.} and Shereshovets, {V. V.} and Shishlov, {N. M.} and Khalizov, {A. F.} and Komissarov, {V. D.}",

year = "1994",

month = jun,

doi = "10.1007/BF02067795",

language = "English (US)",

volume = "52",

pages = "249--254",

journal = "Reaction Kinetics & Catalysis Letters",

issn = "0133-1736",

publisher = "Springer Netherlands",

number = "2",

}

TY - JOUR

T1 - ESR studies of radical breakdown for di-t-butyl trioxide

AU - Khursan, S. L.

AU - Shereshovets, V. V.

AU - Shishlov, N. M.

AU - Khalizov, A. F.

AU - Komissarov, V. D.

PY - 1994/6

Y1 - 1994/6

N2 - ESR data show thermal breakdown of the title trioxide into peroxy and alkoxy radicals ROO. and RO., respectively. Equilibrium constants were calculated for the formation of tetroxide ROOOOR from two peroxy radicals. Their thermodynamic parameters were determined at temperatures ranging within 193-173 K.

AB - ESR data show thermal breakdown of the title trioxide into peroxy and alkoxy radicals ROO. and RO., respectively. Equilibrium constants were calculated for the formation of tetroxide ROOOOR from two peroxy radicals. Their thermodynamic parameters were determined at temperatures ranging within 193-173 K.

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U2 - 10.1007/BF02067795

DO - 10.1007/BF02067795

M3 - Article

AN - SCOPUS:0028459611

SN - 0133-1736

VL - 52

SP - 249

EP - 254

JO - Reaction Kinetics & Catalysis Letters

JF - Reaction Kinetics & Catalysis Letters

IS - 2

ER -

ESR studies of radical breakdown for di-t-butyl trioxide

Abstract

All Science Journal Classification (ASJC) codes

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