Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring p K_a Effects and Demonstrating Electrocatalysis

Keyphrases

• Electrocatalysis 100%
• Nitrogen Fixation 100%
• Metallocenes 100%
• N2RR 100%
• PK a 100%
• Hydrogen Evolution Reaction 50%
• N-H Bond 50%
• DFT Study 50%
• Anilinium Salt 50%
• Small Molecules 25%
• Substrate Selectivity 25%
• Thermodynamics 25%
• Proton 25%
• Strong Correlation 25%
• Protonation 25%
• Tris 25%
• Cocatalyst 25%
• Multi-electron 25%
• Increased Yield 25%
• Molecular Catalyst 25%
• Catalyst Design 25%
• Triflate 25%
• Phosphine-boranes 25%
• N2 Reduction Reaction 25%
• NH3 Conversion 25%
• Controlled Potential Electrolysis 25%
• Nitrogen Reduction Reaction 25%
• Bond-forming Reactions 25%
• Iron I 25%
• Electrocatalytic Nitrogen Fixation 25%

Chemistry

• Ammonia 100%
• Metallocene 100%
• Electrocatalysis 100%
• Nitrogen Fixation 100%
• Acid Dissociation Constant 100%
• Density Functional Theory 66%
• Hydrogen 66%
• Donor 33%
• Tris 33%
• Carbon Dioxide 33%
• Borane 33%
• Catalyst Design 33%
• Nitrogen Reduction Reaction 33%
• Triflate 33%