Heating rate effects in the transient nucleation problem

Vitaly A. Shneidman

doi:10.1063/1.2768032

Heating rate effects in the transient nucleation problem

Vitaly A. Shneidman

Physics

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9 Scopus citations

Abstract

The matched asymptotic (singular perturbation) treatment of the nucleation equation [V. A. Shneidman, Sov. Phys. Tech. Phys. 32, 76 (1987); 33, 1338 (1988)] is modified to include finite heating rate effects, which follow the isothermal transient stage. Despite the complicated mathematical structure of the discrete Becker-Döring equation, the obtained analytical solution is shown to be accurate numerically. The described situation is typical for two-step annealing crystallization studies and can lead to reinterpretation of some of the classical experiments.

Original language	English (US)
Article number	041102
Journal	Journal of Chemical Physics
Volume	127
Issue number	4
DOIs	https://doi.org/10.1063/1.2768032
State	Published - 2007

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.2768032

Cite this

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Heating rate effects in the transient nucleation problem

Abstract

All Science Journal Classification (ASJC) codes

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