@article{3c938264c65241a1b1d8daf040bdd9a8,
title = " High-Pressure Synthesis of Lu 2 NiIrO 6 with Ferrimagnetism and Large Coercivity ",
abstract = " Double-perovskite Lu 2 NiIrO 6 was synthesized at high pressure (6 GPa) and high temperature (1300 °C). Synchrotron powder X-ray diffraction indicates that its structure is a monoclinic double perovskite (space group P2 1 /n) with a small, 11% Ni/Ir antisite disorder. X-ray absorption near-edge spectroscopy measurements established Ni 2 and Ir 4 formal oxidation states. Magnetic studies indicate a ferrimagnetic transition at 207 K. The low-temperature magnetization curve of Lu 2 NiIrO 6 features broad hysteresis with a coercive field as high as 48 kOe. These results encourage the search for hard magnets in the class of 3d/5d double-perovskite oxides.",
author = "Feng, {Hai L.} and Zheng Deng and Meixia Wu and Mark Croft and Lapidus, {Saul H.} and Sizhan Liu and Tyson, {Trevor A.} and Ravel, {Bruce D.} and Quackenbush, {Nicholas F.} and Frank, {Corey E.} and Changqing Jin and Li, {Man Rong} and David Walker and Martha Greenblatt",
note = "Funding Information: The work of H.L.F. and M.G. was supported by NSF-DMR 1507252 grant. The works at IOPCAS are supported by NSF & MOST of China through research projects. Part of the work was done at the NSLS II, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Brookhaven National Laboratory under contract no. DE-SC0012704. The authors wish to thank the NSLS-II scientists Klaus Attenkofer and Eli Stavitski for valuable help in the NSLS-II work. Use of the Advanced Photon Source at Argonne National Laboratory was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under contract no. DE-AC02-06CH11357. Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",
year = "2019",
month = jan,
day = "7",
doi = "10.1021/acs.inorgchem.8b02557",
language = "English (US)",
volume = "58",
pages = "397--404",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "1",
}