Infrared nano-spectroscopy of ferroelastic domain walls in hybrid improper ferroelectric Ca3Ti2O7

K. A. Smith, E. A. Nowadnick, S. Fan, O. Khatib, S. J. Lim, B. Gao, N. C. Harms, S. N. Neal, J. K. Kirkland, M. C. Martin, C. J. Won, M. B. Raschke, S. W. Cheong, C. J. Fennie, G. L. Carr, H. A. Bechtel, J. L. Musfeldt

Research output: Contribution to journalArticlepeer-review

18 Scopus citations


Ferroic materials are well known to exhibit heterogeneity in the form of domain walls. Understanding the properties of these boundaries is crucial for controlling functionality with external stimuli and for realizing their potential for ultra-low power memory and logic devices as well as novel computing architectures. In this work, we employ synchrotron-based near-field infrared nano-spectroscopy to reveal the vibrational properties of ferroelastic (90 ferroelectric) domain walls in the hybrid improper ferroelectric Ca3Ti2O7. By locally mapping the Ti-O stretching and Ti-O-Ti bending modes, we reveal how structural order parameters rotate across a wall. Thus, we link observed near-field amplitude changes to underlying structural modulations and test ferroelectric switching models against real space measurements of local structure. This initiative opens the door to broadband infrared nano-imaging of heterogeneity in ferroics.

Original languageEnglish (US)
Article number5235
JournalNature communications
Issue number1
StatePublished - Dec 1 2019

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • General Biochemistry, Genetics and Molecular Biology
  • General Physics and Astronomy


Dive into the research topics of 'Infrared nano-spectroscopy of ferroelastic domain walls in hybrid improper ferroelectric Ca3Ti2O7'. Together they form a unique fingerprint.

Cite this