Kinetics and products of oxidation of 2-isopropyl-1,3-dioxolane by chlorine dioxide

G. M. Abushakhmina; A. F. Khalizov; S. S. Zlotskii; V. V. Shereshovets; U. B. Imashev

doi:10.1023/A:1010391405815

Kinetics and products of oxidation of 2-isopropyl-1,3-dioxolane by chlorine dioxide

G. M. Abushakhmina, A. F. Khalizov, S. S. Zlotskii, V. V. Shereshovets, U. B. Imashev

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Chlorine dioxide oxidizes readily 2-isopropyl-1,3-dioxolane (1) in CH₂Cl₂, affording 2-hydroxyethyl isobutyrate. When the reaction is carried out in CHCl₃ or CCl₄, an additional product, 2-chloroethyl isobutyrate, forms in a comparable yield. Kinetics of the reaction follows a second order law -d[ClO₂]/dt = k [ClO₂][1] with the rate constant 1gk = (9.0 ± 1.9) - (17.3 ± 2.6)/θ [L/(mol s)], θ = 2.303 RT kcal/mol.

Original language	English (US)
Pages (from-to)	177-182
Number of pages	6
Journal	Reaction Kinetics and Catalysis Letters
Volume	70
Issue number	1
DOIs	https://doi.org/10.1023/A:1010391405815
State	Published - 2000
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Physical and Theoretical Chemistry

Keywords

Chlorine dioxide
Dioxolanes
Free radicals
Reaction kinetics

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10.1023/A:1010391405815

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title = "Kinetics and products of oxidation of 2-isopropyl-1,3-dioxolane by chlorine dioxide",

abstract = "Chlorine dioxide oxidizes readily 2-isopropyl-1,3-dioxolane (1) in CH2Cl2, affording 2-hydroxyethyl isobutyrate. When the reaction is carried out in CHCl3 or CCl4, an additional product, 2-chloroethyl isobutyrate, forms in a comparable yield. Kinetics of the reaction follows a second order law -d[ClO2]/dt = k [ClO2][1] with the rate constant 1gk = (9.0 ± 1.9) - (17.3 ± 2.6)/θ [L/(mol s)], θ = 2.303 RT kcal/mol.",

keywords = "Chlorine dioxide, Dioxolanes, Free radicals, Reaction kinetics",

author = "Abushakhmina, {G. M.} and Khalizov, {A. F.} and Zlotskii, {S. S.} and Shereshovets, {V. V.} and Imashev, {U. B.}",

year = "2000",

doi = "10.1023/A:1010391405815",

language = "English (US)",

volume = "70",

pages = "177--182",

journal = "Reaction Kinetics and Catalysis Letters",

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TY - JOUR

T1 - Kinetics and products of oxidation of 2-isopropyl-1,3-dioxolane by chlorine dioxide

AU - Abushakhmina, G. M.

AU - Khalizov, A. F.

AU - Zlotskii, S. S.

AU - Shereshovets, V. V.

AU - Imashev, U. B.

PY - 2000

Y1 - 2000

N2 - Chlorine dioxide oxidizes readily 2-isopropyl-1,3-dioxolane (1) in CH2Cl2, affording 2-hydroxyethyl isobutyrate. When the reaction is carried out in CHCl3 or CCl4, an additional product, 2-chloroethyl isobutyrate, forms in a comparable yield. Kinetics of the reaction follows a second order law -d[ClO2]/dt = k [ClO2][1] with the rate constant 1gk = (9.0 ± 1.9) - (17.3 ± 2.6)/θ [L/(mol s)], θ = 2.303 RT kcal/mol.

AB - Chlorine dioxide oxidizes readily 2-isopropyl-1,3-dioxolane (1) in CH2Cl2, affording 2-hydroxyethyl isobutyrate. When the reaction is carried out in CHCl3 or CCl4, an additional product, 2-chloroethyl isobutyrate, forms in a comparable yield. Kinetics of the reaction follows a second order law -d[ClO2]/dt = k [ClO2][1] with the rate constant 1gk = (9.0 ± 1.9) - (17.3 ± 2.6)/θ [L/(mol s)], θ = 2.303 RT kcal/mol.

KW - Chlorine dioxide

KW - Dioxolanes

KW - Free radicals

KW - Reaction kinetics

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Kinetics and products of oxidation of 2-isopropyl-1,3-dioxolane by chlorine dioxide

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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