Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu3LiRu2O6

Bin Huang; Ziyi Liu; Yifeng Han; Shuang Zhao; Meixia Wu; Corey E. Frank; Martha Greenblatt; Mark Croft; Nicholas F. Quackenbush; Sizhan Liu; Trevor A. Tyson; Lei Zhang; Junliang Sun; Pengfei Shan; Jianhong Dai; Xiaohui Yu; Jinguang Cheng; Man Rong Li

doi:10.1039/c9cc06691h

Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu₃LiRu₂O₆

Bin Huang, Ziyi Liu, Yifeng Han, Shuang Zhao, Meixia Wu, Corey E. Frank, Martha Greenblatt, Mark Croft, Nicholas F. Quackenbush, Sizhan Liu, Trevor A. Tyson, Lei Zhang, Junliang Sun, Pengfei Shan, Jianhong Dai, Xiaohui Yu, Jinguang Cheng, Man Rong Li

Physics

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The novel two-dimensional honeycomb layered Cu₃LiRu₂O₆ exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which contradict the large specific-heat Sommerfeld coefficient for metals, and indicate a possible spin-excitation induced nonmetallic metal. This nonmetallic feature can be significantly suppressed by pressure toward producing a bad-metal state, as reflected by the temperature-dependent resistivity response up to 35 GPa.

Original language	English (US)
Pages (from-to)	265-268
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	2
DOIs	https://doi.org/10.1039/c9cc06691h
State	Published - 2019

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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10.1039/c9cc06691h

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Huang, B., Liu, Z., Han, Y., Zhao, S., Wu, M., Frank, C. E., Greenblatt, M., Croft, M., Quackenbush, N. F., Liu, S., Tyson, T. A., Zhang, L., Sun, J., Shan, P., Dai, J., Yu, X., Cheng, J., & Li, M. R. (2019). Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu₃LiRu₂O₆. Chemical Communications, 56(2), 265-268. https://doi.org/10.1039/c9cc06691h

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title = "Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu3LiRu2O6",

abstract = "The novel two-dimensional honeycomb layered Cu3LiRu2O6 exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which contradict the large specific-heat Sommerfeld coefficient for metals, and indicate a possible spin-excitation induced nonmetallic metal. This nonmetallic feature can be significantly suppressed by pressure toward producing a bad-metal state, as reflected by the temperature-dependent resistivity response up to 35 GPa.",

author = "Bin Huang and Ziyi Liu and Yifeng Han and Shuang Zhao and Meixia Wu and Frank, {Corey E.} and Martha Greenblatt and Mark Croft and Quackenbush, {Nicholas F.} and Sizhan Liu and Tyson, {Trevor A.} and Lei Zhang and Junliang Sun and Pengfei Shan and Jianhong Dai and Xiaohui Yu and Jinguang Cheng and Li, {Man Rong}",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc06691h",

language = "English (US)",

volume = "56",

pages = "265--268",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu3LiRu2O6

AU - Huang, Bin

AU - Liu, Ziyi

AU - Han, Yifeng

AU - Zhao, Shuang

AU - Wu, Meixia

AU - Frank, Corey E.

AU - Greenblatt, Martha

AU - Croft, Mark

AU - Quackenbush, Nicholas F.

AU - Liu, Sizhan

AU - Tyson, Trevor A.

AU - Zhang, Lei

AU - Sun, Junliang

AU - Shan, Pengfei

AU - Dai, Jianhong

AU - Yu, Xiaohui

AU - Cheng, Jinguang

AU - Li, Man Rong

PY - 2019

Y1 - 2019

N2 - The novel two-dimensional honeycomb layered Cu3LiRu2O6 exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which contradict the large specific-heat Sommerfeld coefficient for metals, and indicate a possible spin-excitation induced nonmetallic metal. This nonmetallic feature can be significantly suppressed by pressure toward producing a bad-metal state, as reflected by the temperature-dependent resistivity response up to 35 GPa.

AB - The novel two-dimensional honeycomb layered Cu3LiRu2O6 exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which contradict the large specific-heat Sommerfeld coefficient for metals, and indicate a possible spin-excitation induced nonmetallic metal. This nonmetallic feature can be significantly suppressed by pressure toward producing a bad-metal state, as reflected by the temperature-dependent resistivity response up to 35 GPa.

UR - http://www.scopus.com/inward/record.url?scp=85076989011&partnerID=8YFLogxK

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U2 - 10.1039/c9cc06691h

DO - 10.1039/c9cc06691h

M3 - Article

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AN - SCOPUS:85076989011

SN - 1359-7345

VL - 56

SP - 265

EP - 268

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu₃LiRu₂O₆

Abstract

All Science Journal Classification (ASJC) codes

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