Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu3LiRu2O6

Bin Huang; Ziyi Liu; Yifeng Han; Shuang Zhao; Meixia Wu; Corey E. Frank; Martha Greenblatt; Mark Croft; Nicholas F. Quackenbush; Sizhan Liu; Trevor A. Tyson; Lei Zhang; Junliang Sun; Pengfei Shan; Jianhong Dai; Xiaohui Yu; Jinguang Cheng; Man Rong Li

doi:10.1039/c9cc06691h

Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu₃LiRu₂O₆

Bin Huang
, Ziyi Liu
, Yifeng Han
, Shuang Zhao
, Meixia Wu
, Corey E. Frank
, Martha Greenblatt
, Mark Croft
, Nicholas F. Quackenbush
, Sizhan Liu
, Trevor A. Tyson
, Lei Zhang
, Junliang Sun
, Pengfei Shan
, Jianhong Dai
, Xiaohui Yu
, Jinguang Cheng
, Man Rong Li

Physics

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The novel two-dimensional honeycomb layered Cu₃LiRu₂O₆ exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which contradict the large specific-heat Sommerfeld coefficient for metals, and indicate a possible spin-excitation induced nonmetallic metal. This nonmetallic feature can be significantly suppressed by pressure toward producing a bad-metal state, as reflected by the temperature-dependent resistivity response up to 35 GPa.

Original language	English (US)
Pages (from-to)	265-268
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	2
DOIs	https://doi.org/10.1039/c9cc06691h
State	Published - 2019

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c9cc06691h

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Huang, B., Liu, Z., Han, Y., Zhao, S., Wu, M., Frank, C. E., Greenblatt, M., Croft, M., Quackenbush, N. F., Liu, S., Tyson, T. A., Zhang, L., Sun, J., Shan, P., Dai, J., Yu, X., Cheng, J., & Li, M. R. (2019). Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu₃LiRu₂O₆. Chemical Communications, 56(2), 265-268. https://doi.org/10.1039/c9cc06691h

@article{69c4246419104e99bbcd5c0006226175,

title = "Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu3LiRu2O6",

abstract = "The novel two-dimensional honeycomb layered Cu3LiRu2O6 exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which contradict the large specific-heat Sommerfeld coefficient for metals, and indicate a possible spin-excitation induced nonmetallic metal. This nonmetallic feature can be significantly suppressed by pressure toward producing a bad-metal state, as reflected by the temperature-dependent resistivity response up to 35 GPa.",

author = "Bin Huang and Ziyi Liu and Yifeng Han and Shuang Zhao and Meixia Wu and Frank, \{Corey E.\} and Martha Greenblatt and Mark Croft and Quackenbush, \{Nicholas F.\} and Sizhan Liu and Tyson, \{Trevor A.\} and Lei Zhang and Junliang Sun and Pengfei Shan and Jianhong Dai and Xiaohui Yu and Jinguang Cheng and Li, \{Man Rong\}",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc06691h",

language = "English (US)",

volume = "56",

pages = "265--268",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu3LiRu2O6

AU - Huang, Bin

AU - Liu, Ziyi

AU - Han, Yifeng

AU - Zhao, Shuang

AU - Wu, Meixia

AU - Frank, Corey E.

AU - Greenblatt, Martha

AU - Croft, Mark

AU - Quackenbush, Nicholas F.

AU - Liu, Sizhan

AU - Tyson, Trevor A.

AU - Zhang, Lei

AU - Sun, Junliang

AU - Shan, Pengfei

AU - Dai, Jianhong

AU - Yu, Xiaohui

AU - Cheng, Jinguang

AU - Li, Man Rong

PY - 2019

Y1 - 2019

N2 - The novel two-dimensional honeycomb layered Cu3LiRu2O6 exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which contradict the large specific-heat Sommerfeld coefficient for metals, and indicate a possible spin-excitation induced nonmetallic metal. This nonmetallic feature can be significantly suppressed by pressure toward producing a bad-metal state, as reflected by the temperature-dependent resistivity response up to 35 GPa.

AB - The novel two-dimensional honeycomb layered Cu3LiRu2O6 exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which contradict the large specific-heat Sommerfeld coefficient for metals, and indicate a possible spin-excitation induced nonmetallic metal. This nonmetallic feature can be significantly suppressed by pressure toward producing a bad-metal state, as reflected by the temperature-dependent resistivity response up to 35 GPa.

UR - https://www.scopus.com/pages/publications/85076989011

UR - https://www.scopus.com/pages/publications/85076989011#tab=citedBy

U2 - 10.1039/c9cc06691h

DO - 10.1039/c9cc06691h

M3 - Article

C2 - 31807742

AN - SCOPUS:85076989011

SN - 1359-7345

VL - 56

SP - 265

EP - 268

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu₃LiRu₂O₆

Abstract

All Science Journal Classification (ASJC) codes

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