Origin of Nanoscale Friction Contrast between Supported Graphene, MoS2, and a Graphene/MoS2 Heterostructure

Mohammad R. Vazirisereshk, Han Ye, Zhijiang Ye, Alberto Otero-De-La-Roza, Meng Qiang Zhao, Zhaoli Gao, A. T.Charlie Johnson, Erin R. Johnson, Robert W. Carpick, Ashlie Martini

Research output: Contribution to journalArticlepeer-review

112 Scopus citations

Abstract

Ultralow friction can be achieved with 2D materials, particularly graphene and MoS2. The nanotribological properties of these different 2D materials have been measured in previous atomic force microscope (AFM) experiments sequentially, precluding immediate and direct comparison of their frictional behavior. Here, friction is characterized at the nanoscale using AFM experiments with the same tip sliding over graphene, MoS2, and a graphene/MoS2 heterostructure in a single measurement, repeated hundreds of times, and also measured with a slowly varying normal force. The same material systems are simulated using molecular dynamics (MD) and analyzed using density functional theory (DFT) calculations. In both experiments and MD simulations, graphene consistently exhibits lower friction than the MoS2 monolayer and the heterostructure. In some cases, friction on the heterostructure is lower than that on the MoS2 monolayer. Quasi-static MD simulations and DFT calculations show that the origin of the friction contrast is the difference in energy barriers for a tip sliding across each of the three surfaces.

Original languageEnglish (US)
Pages (from-to)5496-5505
Number of pages10
JournalNano Letters
Volume19
Issue number8
DOIs
StatePublished - Aug 14 2019
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics
  • Mechanical Engineering

Keywords

  • Nanoscale friction
  • atomic force microscope
  • density-functional theory
  • graphene versus MoS
  • heterostructure
  • molecular dynamics

Fingerprint

Dive into the research topics of 'Origin of Nanoscale Friction Contrast between Supported Graphene, MoS2, and a Graphene/MoS2 Heterostructure'. Together they form a unique fingerprint.

Cite this