OVERESTIMATION OF THE RATE CONSTANT OF THE Cl plus SiH//4 REACTION DETERMINED UNDER FLOW CONDITIONS DUE TO HETEROGENEOUS PROCESSES.

V. R. Braun; A. I. Chichinin; L. N. Krasnoperov

OVERESTIMATION OF THE RATE CONSTANT OF THE Cl plus SiH//4 REACTION DETERMINED UNDER FLOW CONDITIONS DUE TO HETEROGENEOUS PROCESSES.

V. R. Braun, A. I. Chichinin, L. N. Krasnoperov

Research output: Contribution to journal › Article › peer-review

Abstract

The rate constant of the Cl plus SiH//4 reaction has been measured by laser magnetic resonance under flow conditions. An anomalously high value left bracket (4. 5 plus or minus 1. 7) multiplied by (times) 10** minus **1**0 cm**3/sec right bracket has been obtained. It has been shown that the overestimation of the rate constant of this reaction is caused by heterogeneous processes.

Original language	English (US)
Pages (from-to)	392-398
Number of pages	7
Journal	Kinetics and Catalysis
Volume	26
Issue number	pt 2
State	Published - Mar 1985
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Modeling and Simulation
Computer Science Applications

Cite this

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AB - The rate constant of the Cl plus SiH//4 reaction has been measured by laser magnetic resonance under flow conditions. An anomalously high value left bracket (4. 5 plus or minus 1. 7) multiplied by (times) 10** minus **1**0 cm**3/sec right bracket has been obtained. It has been shown that the overestimation of the rate constant of this reaction is caused by heterogeneous processes.

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OVERESTIMATION OF THE RATE CONSTANT OF THE Cl plus SiH//4 REACTION DETERMINED UNDER FLOW CONDITIONS DUE TO HETEROGENEOUS PROCESSES.

Abstract

All Science Journal Classification (ASJC) codes

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