Photostability of a series of two-photon absorbing flourene derivatives

Kevin D. Belfield, Mykhailo V. Bondar, Olga V. Przhonska, Katherine J. Schafer

Research output: Contribution to journalArticlepeer-review

36 Scopus citations

Abstract

The photochemical stability of a series of two-photon absorbing (TPA) fluorene derivatives was investigated in air- and N2-saturated acetonitrile (ACN) at room temperature. The quantum yields of the photoreactions, Φ, were determined at various concentrations of the fluorene derivatives, oxygen concentration of the solvent, and irradiation wavelength. The absorption and fluorescence spectra of the photoproducts, corresponding to different excitation conditions, were analyzed. Photooxidation and electron transfer processes are proposed as photobleaching mechanisms for the fluorene derivatives in ACN. The relatively low photochemical quantum yields (Φ∼10-4) make the derivatives particularly promising for linear and nonlinear optical applications.

Original languageEnglish (US)
Pages (from-to)489-496
Number of pages8
JournalJournal of Photochemistry and Photobiology A: Chemistry
Volume162
Issue number2-3
DOIs
StatePublished - Mar 15 2004
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Physics and Astronomy(all)

Keywords

  • Fluorene derivatives
  • Photochemical quantum yield
  • Photooxidation
  • Photostability

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