Polar acetalization and transacetalization in the gas phase: The Eberlin reaction

R. Graham Cooks; Hao Chen; Marcos N. Eberlin; Xubin Zheng; W. Andy Tao

doi:10.1021/cr0400921

Polar acetalization and transacetalization in the gas phase: The Eberlin reaction

R. Graham Cooks, Hao Chen, Marcos N. Eberlin, Xubin Zheng, W. Andy Tao

Research output: Contribution to journal › Review article › peer-review

78 Scopus citations

Abstract

An overview of the large body of work published on the Eberlin acetalization and transacetalization reactions and related gas phase ion/molecule reactions is given. The reaction occurs for many classes of amphoteric cations with dual Lewis acidity and basicity with cyclic acetals, diols, and related compounds. Extensive fundamental, synthetic, and analytical applications of the gas-phase Eberlin reaction, as well as close connections with condensed-phase chemistry are reviewed.

Original language	English (US)
Pages (from-to)	188-211
Number of pages	24
Journal	Chemical Reviews
Volume	106
Issue number	1
DOIs	https://doi.org/10.1021/cr0400921
State	Published - Jan 2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry

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10.1021/cr0400921

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abstract = "An overview of the large body of work published on the Eberlin acetalization and transacetalization reactions and related gas phase ion/molecule reactions is given. The reaction occurs for many classes of amphoteric cations with dual Lewis acidity and basicity with cyclic acetals, diols, and related compounds. Extensive fundamental, synthetic, and analytical applications of the gas-phase Eberlin reaction, as well as close connections with condensed-phase chemistry are reviewed.",

author = "Cooks, {R. Graham} and Hao Chen and Eberlin, {Marcos N.} and Xubin Zheng and Tao, {W. Andy}",

year = "2006",

month = jan,

doi = "10.1021/cr0400921",

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volume = "106",

pages = "188--211",

journal = "Chemical Reviews",

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T1 - Polar acetalization and transacetalization in the gas phase

T2 - The Eberlin reaction

AU - Cooks, R. Graham

AU - Chen, Hao

AU - Eberlin, Marcos N.

AU - Zheng, Xubin

AU - Tao, W. Andy

PY - 2006/1

Y1 - 2006/1

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AB - An overview of the large body of work published on the Eberlin acetalization and transacetalization reactions and related gas phase ion/molecule reactions is given. The reaction occurs for many classes of amphoteric cations with dual Lewis acidity and basicity with cyclic acetals, diols, and related compounds. Extensive fundamental, synthetic, and analytical applications of the gas-phase Eberlin reaction, as well as close connections with condensed-phase chemistry are reviewed.

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IS - 1

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Polar acetalization and transacetalization in the gas phase: The Eberlin reaction

Abstract

All Science Journal Classification (ASJC) codes

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