Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage

Chang E. Ren, Meng Qiang Zhao, Taron Makaryan, Joseph Halim, Muhammad Boota, Sankalp Kota, Babak Anasori, Michel W. Barsoum, Yury Gogotsi

Research output: Contribution to journalArticlepeer-review

455 Scopus citations


Herein we develop a chemical etching method to produce porous two-dimensional (2D) Ti3C2Tx MXenes at room temperature in aqueous solutions. The as-produced porous Ti3C2Tx (p-Ti3C2Tx) have larger specific surface areas and more open structures than their pristine counterparts, and can be fabricated into flexible films with, or without, the addition of carbon nanotubes (CNTs). The as-fabricated p-Ti3C2Tx/CNT films showed significantly improved lithium ion storage capabilities compared to pristine Ti3C2Tx based films, with a very high capacity of ≈1250mAhg-1 at 0.1C, excellent cycling stability, and good rate performance (330mAhg-1 at 10C). Using the same chemical etching method, we also made porous Nb2CTx and V2CTx MXenes. Therefore, this study provides a simple, yet effective, procedure to introduce pores into MXenes and possibly other 2D sheets that in turn, can enhance their electrochemical properties.

Original languageEnglish (US)
Pages (from-to)689-693
Number of pages5
Issue number5
StatePublished - May 1 2016
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electrochemistry


  • Etching
  • Li-ion storage
  • MXene
  • Partial oxidation
  • Porous 2D materials


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