TY - JOUR
T1 - Probing surface electrochemical activity of nanomaterials using a hybrid atomic force microscope-scanning electrochemical microscope (Afm-secm)
AU - Shi, Xiaonan
AU - Ma, Qingquan
AU - Marhaba, Taha
AU - Zhang, Wen
N1 - Funding Information:
This work is funded by the national science foundation (Award Number: 1756444) via Biological & Environmental Interfaces of Nano Materials, the USDA National Institute of Food and Agriculture, AFRI project [2018-07549] and Assistance Agreement No. 83945101-0 awarded by the U.S. Environmental Protection Agency to New Jersey Institute of Technology. It has not been formally reviewed by EPA. The views expressed in this document are solely those of authors and do not necessarily reflect those of the Agency. EPA does not endorse any products or commercial services mentioned in this publication. The authors also thank Undergraduate Research and Innovation program (URI) Phase-1 & Phase-2 at New Jersey Institute of Technology.
Publisher Copyright:
© 2021 JoVE Journal of Visualized Experiments.
PY - 2021
Y1 - 2021
N2 - Scanning electrochemical microscopy (SECM) is used to measure the local electrochemical behavior of liquid/solid, liquid/gas and liquid/liquid interfaces. Atomic force microscopy (AFM) is a versatile tool to characterize micro-and nanostructure in terms of topography and mechanical properties. However, conventional SECM or AFM provides limited laterally resolved information on electrical or electrochemical properties at nanoscale. For instance, the activity of a nanomaterial surface at crystal facet levels is difficult to resolve by conventional electrochemistry methods. This paper reports the application of a combination of AFM and SECM, namely, AFM-SECM, to probe nanoscale surface electrochemical activity while acquiring high-resolution topographical data. Such measurements are critical to understanding the relationship between nanostructure and reaction activity, which is relevant to a wide range of applications in material science, life science and chemical processes. The versatility of the combined AFM-SECM is demonstrated by mapping topographical and electrochemical properties of faceted nanoparticles (NPs) and nanobubbles (NBs), respectively. Compared to previously reported SECM imaging of nanostructures, this AFM-SECM enables quantitative assessment of local surface activity or reactivity with higher resolution of surface mapping.
AB - Scanning electrochemical microscopy (SECM) is used to measure the local electrochemical behavior of liquid/solid, liquid/gas and liquid/liquid interfaces. Atomic force microscopy (AFM) is a versatile tool to characterize micro-and nanostructure in terms of topography and mechanical properties. However, conventional SECM or AFM provides limited laterally resolved information on electrical or electrochemical properties at nanoscale. For instance, the activity of a nanomaterial surface at crystal facet levels is difficult to resolve by conventional electrochemistry methods. This paper reports the application of a combination of AFM and SECM, namely, AFM-SECM, to probe nanoscale surface electrochemical activity while acquiring high-resolution topographical data. Such measurements are critical to understanding the relationship between nanostructure and reaction activity, which is relevant to a wide range of applications in material science, life science and chemical processes. The versatility of the combined AFM-SECM is demonstrated by mapping topographical and electrochemical properties of faceted nanoparticles (NPs) and nanobubbles (NBs), respectively. Compared to previously reported SECM imaging of nanostructures, this AFM-SECM enables quantitative assessment of local surface activity or reactivity with higher resolution of surface mapping.
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U2 - 10.3791/61111
DO - 10.3791/61111
M3 - Article
C2 - 33645554
AN - SCOPUS:85101748697
SN - 1940-087X
VL - 2021
SP - 1
EP - 23
JO - Journal of Visualized Experiments
JF - Journal of Visualized Experiments
IS - 168
M1 - e61111
ER -