Process-structure-property relationships of erodable polymeric biomaterials: II - Long range order in poly (desaminotyrosyl arylates)

Michael Jaffe; Zohar Ophir; George Collins; Ali Recber; Seung Uk Yoo; Joseph J. Rafalko

doi:10.1016/S0032-3861(03)00559-7

Process-structure-property relationships of erodable polymeric biomaterials: II - Long range order in poly (desaminotyrosyl arylates)

Michael Jaffe
, Zohar Ophir
, George Collins
, Ali Recber
, Seung Uk Yoo
, Joseph J. Rafalko

New Jersey Innovation Institute

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The long-range order of some bioerodable polyesteramides based on a desaminotyrosyl [Thermochim Acta 396 (2003) 141; Polym Adv Technol 13 (2002) 926; J Am Chem Soc 119 (1997) 4553] diol monomer has been investigated. The order is mesogenic, best described as a 'condis crystal' or smectic-like. In all cases where long-range order is present, ordered H bonds between amide groups are observed. The order stabilizes the polymer to dimensional change and mechanical relaxation under biorelevant conditions.

Original language	English (US)
Pages (from-to)	6033-6042
Number of pages	10
Journal	Polymer
Volume	44
Issue number	19
DOIs	https://doi.org/10.1016/S0032-3861(03)00559-7
State	Published - Aug 21 2003

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Materials Chemistry

Keywords

FT-IR
Hydrogen bonding
Mesogenic bioerodable polyesteramide

Access to Document

10.1016/S0032-3861(03)00559-7

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@article{292ff612c3d341959a0a02639536214b,

title = "Process-structure-property relationships of erodable polymeric biomaterials: II - Long range order in poly (desaminotyrosyl arylates)",

abstract = "The long-range order of some bioerodable polyesteramides based on a desaminotyrosyl [Thermochim Acta 396 (2003) 141; Polym Adv Technol 13 (2002) 926; J Am Chem Soc 119 (1997) 4553] diol monomer has been investigated. The order is mesogenic, best described as a 'condis crystal' or smectic-like. In all cases where long-range order is present, ordered H bonds between amide groups are observed. The order stabilizes the polymer to dimensional change and mechanical relaxation under biorelevant conditions.",

keywords = "FT-IR, Hydrogen bonding, Mesogenic bioerodable polyesteramide",

author = "Michael Jaffe and Zohar Ophir and George Collins and Ali Recber and Yoo, \{Seung Uk\} and Rafalko, \{Joseph J.\}",

note = "Funding Information: The authors thank Professor Joachim Kohn of Rutgers University for his discussions and insights during the progress of this work. The contributions of Professor J. Wu in obtaining and analyzing the X-ray diffract results is appreciated. Discussions with Professor Michael Dunn of the Robert Wood Johnson Medical School and Dr Sharon Bourke of Rutgers University are gratefully acknowledged. Support for this work from the New Jersey Center for Biomaterials, the National Institutes of Health and the NIH—National Institute for Biomedical Imaging and Bioengineering, P41 EB 000922-01 is recognized with thanks.",

year = "2003",

month = aug,

day = "21",

doi = "10.1016/S0032-3861(03)00559-7",

language = "English (US)",

volume = "44",

pages = "6033--6042",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier B.V.",

number = "19",

}

TY - JOUR

T1 - Process-structure-property relationships of erodable polymeric biomaterials

T2 - II - Long range order in poly (desaminotyrosyl arylates)

AU - Jaffe, Michael

AU - Ophir, Zohar

AU - Collins, George

AU - Recber, Ali

AU - Yoo, Seung Uk

AU - Rafalko, Joseph J.

N1 - Funding Information: The authors thank Professor Joachim Kohn of Rutgers University for his discussions and insights during the progress of this work. The contributions of Professor J. Wu in obtaining and analyzing the X-ray diffract results is appreciated. Discussions with Professor Michael Dunn of the Robert Wood Johnson Medical School and Dr Sharon Bourke of Rutgers University are gratefully acknowledged. Support for this work from the New Jersey Center for Biomaterials, the National Institutes of Health and the NIH—National Institute for Biomedical Imaging and Bioengineering, P41 EB 000922-01 is recognized with thanks.

PY - 2003/8/21

Y1 - 2003/8/21

N2 - The long-range order of some bioerodable polyesteramides based on a desaminotyrosyl [Thermochim Acta 396 (2003) 141; Polym Adv Technol 13 (2002) 926; J Am Chem Soc 119 (1997) 4553] diol monomer has been investigated. The order is mesogenic, best described as a 'condis crystal' or smectic-like. In all cases where long-range order is present, ordered H bonds between amide groups are observed. The order stabilizes the polymer to dimensional change and mechanical relaxation under biorelevant conditions.

AB - The long-range order of some bioerodable polyesteramides based on a desaminotyrosyl [Thermochim Acta 396 (2003) 141; Polym Adv Technol 13 (2002) 926; J Am Chem Soc 119 (1997) 4553] diol monomer has been investigated. The order is mesogenic, best described as a 'condis crystal' or smectic-like. In all cases where long-range order is present, ordered H bonds between amide groups are observed. The order stabilizes the polymer to dimensional change and mechanical relaxation under biorelevant conditions.

KW - FT-IR

KW - Hydrogen bonding

KW - Mesogenic bioerodable polyesteramide

UR - https://www.scopus.com/pages/publications/0041378231

UR - https://www.scopus.com/pages/publications/0041378231#tab=citedBy

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DO - 10.1016/S0032-3861(03)00559-7

M3 - Article

AN - SCOPUS:0041378231

SN - 0032-3861

VL - 44

SP - 6033

EP - 6042

JO - Polymer

JF - Polymer

IS - 19

ER -

Process-structure-property relationships of erodable polymeric biomaterials: II - Long range order in poly (desaminotyrosyl arylates)

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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