Redox-controlled interconversion between trigonal prismatic and octahedral geometries in a monodithiolene tetracarbonyl complex of tungsten

Keyphrases

• Tungsten 100%
• Redox 100%
• Interconversion 100%
• Octahedral Geometry 100%
• Prismatic Geometry 100%
• Trigonal Prismatic 100%
• Tetracarbonyl Complexes 100%
• Dithiolene 75%
• Octahedron 50%
• Oxidation State 50%
• Dithiolene Ligands 50%
• Geometry Modification 50%
• Low Energy 25%
• Bonding Interactions 25%
• Density Functional Calculations 25%
• Structural Information 25%
• Piperazine 25%
• Ligand-based 25%
• X-ray Absorption 25%
• Highest Occupied Molecular Orbital 25%
• Electron Paramagnetic Resonance 25%
• Nitrogen Atom 25%
• Divalent 25%
• 2-dimethyl-1 25%
• Sulfur Content 25%
• Configuration Interaction 25%
• Electron Counting 25%
• One-electron Reduction 25%
• One-electron Oxidation 25%
• Dithiolate Ligands 25%
• Cyclic Voltammogram 25%
• Dithiolate 25%
• 1,4-Dimethylpiperazine 25%
• Antibonding 25%
• Metal Oxidation 25%
• Tetracarbonyl 25%
• Trigonal Prism 25%
• Lowest Unoccupied Molecular Orbital 25%
• Two-electron Oxygen Reduction Reaction 25%
• Common Denominator 25%
• Cambridge Structural Database 25%
• Dithione 25%
• Singly Occupied Molecular Orbital 25%
• Sulfate Radical 25%
• Tungsten Ions 25%
• Anodic Peak 25%

Chemistry

• Structure 100%
• Octahedral Crystal 100%
• Density Functional Theory 50%
• EPR Spectroscopy 50%
• Highest Occupied Molecular Orbital 50%
• Nitrogen Atom 50%
• Lowest Unoccupied Molecular Orbital 50%
• Piperazine 50%
• Configuration Interaction 50%
• Molecular Orbital 50%
• Tungsten Ion 50%