Stabilized photoanodes for water oxidation by integration of organic dyes, water oxidation catalysts, and electron-transfer mediators

Degao Wang; Michael S. Eberhart; Matthew V. Sheridan; Ke Hu; Benjamin D. Sherman; Animesh Nayak; Ying Wang; Seth L. Marquard; Christopher J. Dares; Thomas J. Meyer

doi:10.1073/pnas.1802903115

Stabilized photoanodes for water oxidation by integration of organic dyes, water oxidation catalysts, and electron-transfer mediators

Degao Wang
, Michael S. Eberhart
, Matthew V. Sheridan
, Ke Hu
, Benjamin D. Sherman
, Animesh Nayak
, Ying Wang
, Seth L. Marquard
, Christopher J. Dares
, Thomas J. Meyer

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

Stabilized photoanodes for light-driven water oxidation have been prepared on nanoparticle core/shell electrodes with surface-stabilized donor–acceptor chromophores, a water oxidation catalyst, and an electron-transfer mediator. For the electrode, fluorine-doped tin oxide FTOjSnO ₂ /TiO ₂ j-Org1-j1.1 nm Al ₂ O ₃ j-RuP ²⁺ -WOC (water oxidation catalyst) with Org1 (1-cyano-2-(4-(diphenylamino)phenyl)vinyl)phosphonic acid), the mediator RuP ²⁺ ([Ru(4,4-(PO ₃ H ₂ ) ₂ -2,2-bipyridine)(2,2bipyridine) ₂ ] ²⁺ ), and the WOC, Ru(bda)(py(CH ₂ ) _(3or10) P(O ₃ H) ₂ ) ₂ (bda is 2,2-bipyridine-6,6-dicarboxylate with x = 3 or 10), solar excitation resulted in photocurrents of ∼500 μA/cm ² and quantitative O ₂ evolution at pH 4.65. Related results were obtained for other Ru(II) polypyridyl mediators. For the organic dye PP (5-(4-(dihydroxyphosphoryl) phenyl)-10,15,20-Tris(mesityl)porphyrin), solar water oxidation occurred with a driving force near 0 V.

Original language	English (US)
Pages (from-to)	8523-8528
Number of pages	6
Journal	Proceedings of the National Academy of Sciences of the United States of America
Volume	115
Issue number	34
DOIs	https://doi.org/10.1073/pnas.1802903115
State	Published - Aug 21 2018
Externally published	Yes

All Science Journal Classification (ASJC) codes

General

Keywords

Core/shell
DSPEC
Electron-transfer mediator
Organic dye
Water oxidation

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10.1073/pnas.1802903115

Cite this

Wang, D., Eberhart, M. S., Sheridan, M. V., Hu, K., Sherman, B. D., Nayak, A., Wang, Y., Marquard, S. L., Dares, C. J., & Meyer, T. J. (2018). Stabilized photoanodes for water oxidation by integration of organic dyes, water oxidation catalysts, and electron-transfer mediators. Proceedings of the National Academy of Sciences of the United States of America, 115(34), 8523-8528. https://doi.org/10.1073/pnas.1802903115

@article{722cf581596b4db7b4e136b039f33c9c,

title = "Stabilized photoanodes for water oxidation by integration of organic dyes, water oxidation catalysts, and electron-transfer mediators",

abstract = " Stabilized photoanodes for light-driven water oxidation have been prepared on nanoparticle core/shell electrodes with surface-stabilized donor–acceptor chromophores, a water oxidation catalyst, and an electron-transfer mediator. For the electrode, fluorine-doped tin oxide FTOjSnO 2 /TiO 2 j-Org1-j1.1 nm Al 2 O 3 j-RuP 2+ -WOC (water oxidation catalyst) with Org1 (1-cyano-2-(4-(diphenylamino)phenyl)vinyl)phosphonic acid), the mediator RuP 2+ ([Ru(4,4-(PO 3 H 2 ) 2 -2,2-bipyridine)(2,2bipyridine) 2 ] 2+ ), and the WOC, Ru(bda)(py(CH 2 ) (3or10) P(O 3 H) 2 ) 2 (bda is 2,2-bipyridine-6,6-dicarboxylate with x = 3 or 10), solar excitation resulted in photocurrents of ∼500 μA/cm 2 and quantitative O 2 evolution at pH 4.65. Related results were obtained for other Ru(II) polypyridyl mediators. For the organic dye PP (5-(4-(dihydroxyphosphoryl) phenyl)-10,15,20-Tris(mesityl)porphyrin), solar water oxidation occurred with a driving force near 0 V.",

keywords = "Core/shell, DSPEC, Electron-transfer mediator, Organic dye, Water oxidation",

author = "Degao Wang and Eberhart, \{Michael S.\} and Sheridan, \{Matthew V.\} and Ke Hu and Sherman, \{Benjamin D.\} and Animesh Nayak and Ying Wang and Marquard, \{Seth L.\} and Dares, \{Christopher J.\} and Meyer, \{Thomas J.\}",

year = "2018",

month = aug,

day = "21",

doi = "10.1073/pnas.1802903115",

language = "English (US)",

volume = "115",

pages = "8523--8528",

journal = "Proceedings of the National Academy of Sciences of the United States of America",

issn = "0027-8424",

publisher = "National Academy of Sciences",

number = "34",

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Wang, D, Eberhart, MS, Sheridan, MV, Hu, K, Sherman, BD, Nayak, A, Wang, Y, Marquard, SL, Dares, CJ & Meyer, TJ 2018, 'Stabilized photoanodes for water oxidation by integration of organic dyes, water oxidation catalysts, and electron-transfer mediators', Proceedings of the National Academy of Sciences of the United States of America, vol. 115, no. 34, pp. 8523-8528. https://doi.org/10.1073/pnas.1802903115

Stabilized photoanodes for water oxidation by integration of organic dyes, water oxidation catalysts, and electron-transfer mediators. / Wang, Degao; Eberhart, Michael S.; Sheridan, Matthew V. et al.
In: Proceedings of the National Academy of Sciences of the United States of America, Vol. 115, No. 34, 21.08.2018, p. 8523-8528.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Stabilized photoanodes for water oxidation by integration of organic dyes, water oxidation catalysts, and electron-transfer mediators

AU - Wang, Degao

AU - Eberhart, Michael S.

AU - Sheridan, Matthew V.

AU - Hu, Ke

AU - Sherman, Benjamin D.

AU - Nayak, Animesh

AU - Wang, Ying

AU - Marquard, Seth L.

AU - Dares, Christopher J.

AU - Meyer, Thomas J.

PY - 2018/8/21

Y1 - 2018/8/21

N2 - Stabilized photoanodes for light-driven water oxidation have been prepared on nanoparticle core/shell electrodes with surface-stabilized donor–acceptor chromophores, a water oxidation catalyst, and an electron-transfer mediator. For the electrode, fluorine-doped tin oxide FTOjSnO 2 /TiO 2 j-Org1-j1.1 nm Al 2 O 3 j-RuP 2+ -WOC (water oxidation catalyst) with Org1 (1-cyano-2-(4-(diphenylamino)phenyl)vinyl)phosphonic acid), the mediator RuP 2+ ([Ru(4,4-(PO 3 H 2 ) 2 -2,2-bipyridine)(2,2bipyridine) 2 ] 2+ ), and the WOC, Ru(bda)(py(CH 2 ) (3or10) P(O 3 H) 2 ) 2 (bda is 2,2-bipyridine-6,6-dicarboxylate with x = 3 or 10), solar excitation resulted in photocurrents of ∼500 μA/cm 2 and quantitative O 2 evolution at pH 4.65. Related results were obtained for other Ru(II) polypyridyl mediators. For the organic dye PP (5-(4-(dihydroxyphosphoryl) phenyl)-10,15,20-Tris(mesityl)porphyrin), solar water oxidation occurred with a driving force near 0 V.

AB - Stabilized photoanodes for light-driven water oxidation have been prepared on nanoparticle core/shell electrodes with surface-stabilized donor–acceptor chromophores, a water oxidation catalyst, and an electron-transfer mediator. For the electrode, fluorine-doped tin oxide FTOjSnO 2 /TiO 2 j-Org1-j1.1 nm Al 2 O 3 j-RuP 2+ -WOC (water oxidation catalyst) with Org1 (1-cyano-2-(4-(diphenylamino)phenyl)vinyl)phosphonic acid), the mediator RuP 2+ ([Ru(4,4-(PO 3 H 2 ) 2 -2,2-bipyridine)(2,2bipyridine) 2 ] 2+ ), and the WOC, Ru(bda)(py(CH 2 ) (3or10) P(O 3 H) 2 ) 2 (bda is 2,2-bipyridine-6,6-dicarboxylate with x = 3 or 10), solar excitation resulted in photocurrents of ∼500 μA/cm 2 and quantitative O 2 evolution at pH 4.65. Related results were obtained for other Ru(II) polypyridyl mediators. For the organic dye PP (5-(4-(dihydroxyphosphoryl) phenyl)-10,15,20-Tris(mesityl)porphyrin), solar water oxidation occurred with a driving force near 0 V.

KW - Core/shell

KW - DSPEC

KW - Electron-transfer mediator

KW - Organic dye

KW - Water oxidation

UR - https://www.scopus.com/pages/publications/85051765474

UR - https://www.scopus.com/pages/publications/85051765474#tab=citedBy

U2 - 10.1073/pnas.1802903115

DO - 10.1073/pnas.1802903115

M3 - Article

C2 - 30082396

AN - SCOPUS:85051765474

SN - 0027-8424

VL - 115

SP - 8523

EP - 8528

JO - Proceedings of the National Academy of Sciences of the United States of America

JF - Proceedings of the National Academy of Sciences of the United States of America

IS - 34

ER -

Stabilized photoanodes for water oxidation by integration of organic dyes, water oxidation catalysts, and electron-transfer mediators

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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