TY - JOUR
T1 - Stable 2D Bisthienoacenes
T2 - Synthesis, Crystal Packing, and Photophysical Properties
AU - Wang, Zunzhi
AU - Li, Jinfeng
AU - Zhang, Simeng
AU - Wang, Qi
AU - Dai, Gaole
AU - Liu, Bingqing
AU - Zhu, Xiaolin
AU - Li, Zhongguo
AU - Kolodziej, Charles
AU - McCleese, Christopher
AU - Burda, Clemens
AU - Sun, Wenfang
AU - Chen, Long
N1 - Publisher Copyright:
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2018/9/25
Y1 - 2018/9/25
N2 - Two novel 2D bisthienoacenes with annulated thiophene units at different positions were developed. Both 1,2- and 1,4-addition of the α,β-unsaturated ketone moieties lead to the major formation of four-fold alkylsilylethynyl substituted 2D heteroacenes (namely BTT-4TIPS and BTP-4TIPS). The photophysical, electrochemical properties, crystal packing structures, and charge carrier transport performances were investigated in detail.
AB - Two novel 2D bisthienoacenes with annulated thiophene units at different positions were developed. Both 1,2- and 1,4-addition of the α,β-unsaturated ketone moieties lead to the major formation of four-fold alkylsilylethynyl substituted 2D heteroacenes (namely BTT-4TIPS and BTP-4TIPS). The photophysical, electrochemical properties, crystal packing structures, and charge carrier transport performances were investigated in detail.
KW - 2D acenes
KW - crystal packing
KW - heteroacenes
KW - photophysical properties
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U2 - 10.1002/chem.201802411
DO - 10.1002/chem.201802411
M3 - Article
AN - SCOPUS:85052911461
SN - 0947-6539
VL - 24
SP - 14442
EP - 14447
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 54
ER -