Stable 2D Bisthienoacenes: Synthesis, Crystal Packing, and Photophysical Properties

Zunzhi Wang; Jinfeng Li; Simeng Zhang; Qi Wang; Gaole Dai; Bingqing Liu; Xiaolin Zhu; Zhongguo Li; Charles Kolodziej; Christopher McCleese; Clemens Burda; Wenfang Sun; Long Chen

doi:10.1002/chem.201802411

Stable 2D Bisthienoacenes: Synthesis, Crystal Packing, and Photophysical Properties

Zunzhi Wang
, Jinfeng Li
, Simeng Zhang
, Qi Wang
, Gaole Dai
, Bingqing Liu
, Xiaolin Zhu
, Zhongguo Li
, Charles Kolodziej
, Christopher McCleese
, Clemens Burda
, Wenfang Sun
, Long Chen

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Two novel 2D bisthienoacenes with annulated thiophene units at different positions were developed. Both 1,2- and 1,4-addition of the α,β-unsaturated ketone moieties lead to the major formation of four-fold alkylsilylethynyl substituted 2D heteroacenes (namely BTT-4TIPS and BTP-4TIPS). The photophysical, electrochemical properties, crystal packing structures, and charge carrier transport performances were investigated in detail.

Original language	English (US)
Pages (from-to)	14442-14447
Number of pages	6
Journal	Chemistry - A European Journal
Volume	24
Issue number	54
DOIs	https://doi.org/10.1002/chem.201802411
State	Published - Sep 25 2018
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Organic Chemistry

Keywords

2D acenes
crystal packing
heteroacenes
photophysical properties

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10.1002/chem.201802411

Cite this

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abstract = "Two novel 2D bisthienoacenes with annulated thiophene units at different positions were developed. Both 1,2- and 1,4-addition of the α,β-unsaturated ketone moieties lead to the major formation of four-fold alkylsilylethynyl substituted 2D heteroacenes (namely BTT-4TIPS and BTP-4TIPS). The photophysical, electrochemical properties, crystal packing structures, and charge carrier transport performances were investigated in detail.",

keywords = "2D acenes, crystal packing, heteroacenes, photophysical properties",

author = "Zunzhi Wang and Jinfeng Li and Simeng Zhang and Qi Wang and Gaole Dai and Bingqing Liu and Xiaolin Zhu and Zhongguo Li and Charles Kolodziej and Christopher McCleese and Clemens Burda and Wenfang Sun and Long Chen",

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doi = "10.1002/chem.201802411",

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T1 - Stable 2D Bisthienoacenes

T2 - Synthesis, Crystal Packing, and Photophysical Properties

AU - Wang, Zunzhi

AU - Li, Jinfeng

AU - Zhang, Simeng

AU - Wang, Qi

AU - Dai, Gaole

AU - Liu, Bingqing

AU - Zhu, Xiaolin

AU - Li, Zhongguo

AU - Kolodziej, Charles

AU - McCleese, Christopher

AU - Burda, Clemens

AU - Sun, Wenfang

AU - Chen, Long

PY - 2018/9/25

Y1 - 2018/9/25

N2 - Two novel 2D bisthienoacenes with annulated thiophene units at different positions were developed. Both 1,2- and 1,4-addition of the α,β-unsaturated ketone moieties lead to the major formation of four-fold alkylsilylethynyl substituted 2D heteroacenes (namely BTT-4TIPS and BTP-4TIPS). The photophysical, electrochemical properties, crystal packing structures, and charge carrier transport performances were investigated in detail.

AB - Two novel 2D bisthienoacenes with annulated thiophene units at different positions were developed. Both 1,2- and 1,4-addition of the α,β-unsaturated ketone moieties lead to the major formation of four-fold alkylsilylethynyl substituted 2D heteroacenes (namely BTT-4TIPS and BTP-4TIPS). The photophysical, electrochemical properties, crystal packing structures, and charge carrier transport performances were investigated in detail.

KW - 2D acenes

KW - crystal packing

KW - heteroacenes

KW - photophysical properties

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UR - https://www.scopus.com/pages/publications/85052911461#tab=citedBy

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DO - 10.1002/chem.201802411

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AN - SCOPUS:85052911461

SN - 0947-6539

VL - 24

SP - 14442

EP - 14447

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 54

ER -

Stable 2D Bisthienoacenes: Synthesis, Crystal Packing, and Photophysical Properties

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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