Stable 2D Bisthienoacenes: Synthesis, Crystal Packing, and Photophysical Properties

  • Zunzhi Wang
  • , Jinfeng Li
  • , Simeng Zhang
  • , Qi Wang
  • , Gaole Dai
  • , Bingqing Liu
  • , Xiaolin Zhu
  • , Zhongguo Li
  • , Charles Kolodziej
  • , Christopher McCleese
  • , Clemens Burda
  • , Wenfang Sun
  • , Long Chen

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

Two novel 2D bisthienoacenes with annulated thiophene units at different positions were developed. Both 1,2- and 1,4-addition of the α,β-unsaturated ketone moieties lead to the major formation of four-fold alkylsilylethynyl substituted 2D heteroacenes (namely BTT-4TIPS and BTP-4TIPS). The photophysical, electrochemical properties, crystal packing structures, and charge carrier transport performances were investigated in detail.

Original languageEnglish (US)
Pages (from-to)14442-14447
Number of pages6
JournalChemistry - A European Journal
Volume24
Issue number54
DOIs
StatePublished - Sep 25 2018
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • General Chemistry
  • Organic Chemistry

Keywords

  • 2D acenes
  • crystal packing
  • heteroacenes
  • photophysical properties

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