Abstract
X-ray studies of tetrathiafulvalenium-thiocyanate [TTF(SCN)0.588] show a Peierls instability with one-dimensional charge-density waves near 300 K followed by three-dimensional order at Tc=180 K. Below Tc, an interchain competition between both elastic forces and Coulomb interactions drives a temperature-dependent monoclinic strain. A Landau theory including both charge-density and strain order parameters describes the relative TTF chain slip and the superlattice phase variation.
Original language | English (US) |
---|---|
Pages (from-to) | 486-490 |
Number of pages | 5 |
Journal | Physical Review Letters |
Volume | 41 |
Issue number | 7 |
DOIs | |
State | Published - 1978 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- General Physics and Astronomy