Surface immobilized copper(i) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion

Michael S. Eberhart; Brian T. Phelan; Jens Niklas; Emily A. Sprague-Klein; David M. Kaphan; David J. Gosztola; Lin X. Chen; David M. Tiede; Oleg G. Poluektov; Karen L. Mulfort

doi:10.1039/d0cc05972b

Surface immobilized copper(i) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion

Michael S. Eberhart, Brian T. Phelan, Jens Niklas, Emily A. Sprague-Klein, David M. Kaphan, David J. Gosztola, Lin X. Chen, David M. Tiede, Oleg G. Poluektov, Karen L. Mulfort

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Heteroleptic copper(i) bis(phenanthroline) complexes with surface anchoring carboxylate groups have been synthesized and immobilized on nanoporous metal oxide substrates. The species investigated are responsive to the external environment and this work provides a new strategy to control charge transfer processes for efficient solar energy conversion.

Original language	English (US)
Pages (from-to)	12130-12133
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	81
DOIs	https://doi.org/10.1039/d0cc05972b
State	Published - Oct 18 2020
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d0cc05972b

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Eberhart, M. S., Phelan, B. T., Niklas, J., Sprague-Klein, E. A., Kaphan, D. M., Gosztola, D. J., Chen, L. X., Tiede, D. M., Poluektov, O. G., & Mulfort, K. L. (2020). Surface immobilized copper(i) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion. Chemical Communications, 56(81), 12130-12133. https://doi.org/10.1039/d0cc05972b

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title = "Surface immobilized copper(i) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion",

abstract = "Heteroleptic copper(i) bis(phenanthroline) complexes with surface anchoring carboxylate groups have been synthesized and immobilized on nanoporous metal oxide substrates. The species investigated are responsive to the external environment and this work provides a new strategy to control charge transfer processes for efficient solar energy conversion.",

author = "Eberhart, {Michael S.} and Phelan, {Brian T.} and Jens Niklas and Sprague-Klein, {Emily A.} and Kaphan, {David M.} and Gosztola, {David J.} and Chen, {Lin X.} and Tiede, {David M.} and Poluektov, {Oleg G.} and Mulfort, {Karen L.}",

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year = "2020",

month = oct,

day = "18",

doi = "10.1039/d0cc05972b",

language = "English (US)",

volume = "56",

pages = "12130--12133",

journal = "Chemical Communications",

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Eberhart, MS, Phelan, BT, Niklas, J, Sprague-Klein, EA, Kaphan, DM, Gosztola, DJ, Chen, LX, Tiede, DM, Poluektov, OG & Mulfort, KL 2020, 'Surface immobilized copper(i) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion', Chemical Communications, vol. 56, no. 81, pp. 12130-12133. https://doi.org/10.1039/d0cc05972b

TY - JOUR

T1 - Surface immobilized copper(i) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion

AU - Eberhart, Michael S.

AU - Phelan, Brian T.

AU - Niklas, Jens

AU - Sprague-Klein, Emily A.

AU - Kaphan, David M.

AU - Gosztola, David J.

AU - Chen, Lin X.

AU - Tiede, David M.

AU - Poluektov, Oleg G.

AU - Mulfort, Karen L.

PY - 2020/10/18

Y1 - 2020/10/18

N2 - Heteroleptic copper(i) bis(phenanthroline) complexes with surface anchoring carboxylate groups have been synthesized and immobilized on nanoporous metal oxide substrates. The species investigated are responsive to the external environment and this work provides a new strategy to control charge transfer processes for efficient solar energy conversion.

AB - Heteroleptic copper(i) bis(phenanthroline) complexes with surface anchoring carboxylate groups have been synthesized and immobilized on nanoporous metal oxide substrates. The species investigated are responsive to the external environment and this work provides a new strategy to control charge transfer processes for efficient solar energy conversion.

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DO - 10.1039/d0cc05972b

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AN - SCOPUS:85092687408

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

IS - 81

ER -

Surface immobilized copper(i) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion

Abstract

All Science Journal Classification (ASJC) codes

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