Synthesis and characterization of novel rigid two-photon absorbing polymers

Kevin D. Belfield, Sheng Yao, Alma R. Morales, Joel M. Hales, David J. Hagan, Eric W. Van Stryland, Victor M. Chapela, Judith Percino

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

Two-photon absorbing polymers with alternating fluorenyl units as a π-conjugated bridge and bisbenzothiazole or thiazolothiazole as electron-acceptors were synthesized and characterized by IR, elemental analysis, absorption and fluorescence spectroscopy, and thermogravimetric analysis (TGA). Improvement on the solubility was observed in comparison with their phenyl based analogies. The linear absorption and emission spectra were recorded and high fluorescence quantum yields were found. Relatively large two-photon absorption cross-section per repeat unit (420 GM) were measured under fs-pulsed laser excitation.

Original languageEnglish (US)
Pages (from-to)150-155
Number of pages6
JournalPolymers for Advanced Technologies
Volume16
Issue number2-3
DOIs
StatePublished - Feb 1 2005
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics

Keywords

  • Benzothiazole
  • Fluorescence
  • Synthesis
  • Thermogravimetric analysis
  • Thiazolothiazole

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