Synthesis of polysiloxanes bearing di- or triarylamines and NLO chromophores

Kevin D. Belfield; Ousama Najjar; Silvester M. Pius

Synthesis of polysiloxanes bearing di- or triarylamines and NLO chromophores

Kevin D. Belfield, Ousama Najjar, Silvester M. Pius

Research output: Contribution to journal › Conference article › peer-review

Abstract

A series of three highly efficient reactions, Pt-catalyzed hydrosilation, regiospecific bromination, and Pd-catalyzed cross coupling, were performed on a siloxane polymer. This led to the formation of new; highly functionalized polysiloxanes that exhibit second-order nonlinear optical and photoconductive properties. Relatively efficient formation of the stilbene moieties produced siloxane polymers in which each repeat unit bears a charge transporting moiety and an arylamine-based NLO chromophore.

Original language	English (US)
Pages (from-to)	445-446
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	39
Issue number	2
State	Published - Aug 1998
Externally published	Yes
Event	Proceedings of the 1997 Boston Meeting - Boston, MA, USA Duration: Aug 23 1998 → Aug 27 1998

All Science Journal Classification (ASJC) codes

Polymers and Plastics

Cite this

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title = "Synthesis of polysiloxanes bearing di- or triarylamines and NLO chromophores",

abstract = "A series of three highly efficient reactions, Pt-catalyzed hydrosilation, regiospecific bromination, and Pd-catalyzed cross coupling, were performed on a siloxane polymer. This led to the formation of new; highly functionalized polysiloxanes that exhibit second-order nonlinear optical and photoconductive properties. Relatively efficient formation of the stilbene moieties produced siloxane polymers in which each repeat unit bears a charge transporting moiety and an arylamine-based NLO chromophore.",

author = "Belfield, {Kevin D.} and Ousama Najjar and Pius, {Silvester M.}",

year = "1998",

month = aug,

language = "English (US)",

volume = "39",

pages = "445--446",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

issn = "0032-3934",

number = "2",

note = "Proceedings of the 1997 Boston Meeting ; Conference date: 23-08-1998 Through 27-08-1998",

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TY - JOUR

T1 - Synthesis of polysiloxanes bearing di- or triarylamines and NLO chromophores

AU - Belfield, Kevin D.

AU - Najjar, Ousama

AU - Pius, Silvester M.

PY - 1998/8

Y1 - 1998/8

N2 - A series of three highly efficient reactions, Pt-catalyzed hydrosilation, regiospecific bromination, and Pd-catalyzed cross coupling, were performed on a siloxane polymer. This led to the formation of new; highly functionalized polysiloxanes that exhibit second-order nonlinear optical and photoconductive properties. Relatively efficient formation of the stilbene moieties produced siloxane polymers in which each repeat unit bears a charge transporting moiety and an arylamine-based NLO chromophore.

AB - A series of three highly efficient reactions, Pt-catalyzed hydrosilation, regiospecific bromination, and Pd-catalyzed cross coupling, were performed on a siloxane polymer. This led to the formation of new; highly functionalized polysiloxanes that exhibit second-order nonlinear optical and photoconductive properties. Relatively efficient formation of the stilbene moieties produced siloxane polymers in which each repeat unit bears a charge transporting moiety and an arylamine-based NLO chromophore.

UR - http://www.scopus.com/inward/record.url?scp=0032136524&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032136524&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0032136524

SN - 0032-3934

VL - 39

SP - 445

EP - 446

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 2

T2 - Proceedings of the 1997 Boston Meeting

Y2 - 23 August 1998 through 27 August 1998

ER -

Synthesis of polysiloxanes bearing di- or triarylamines and NLO chromophores

Abstract

All Science Journal Classification (ASJC) codes

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