Synthesis of polysiloxanes bearing di- or triarylamines and NLO chromophores

Kevin Belfield; Ousama Najjar; Silvester M. Pius

Synthesis of polysiloxanes bearing di- or triarylamines and NLO chromophores

Kevin Belfield, Ousama Najjar, Silvester M. Pius

Research output: Contribution to journal › Conference article › peer-review

Abstract

A series of three highly efficient reactions, Pt-catalyzed hydrosilation, regiospecific bromination, and Pd-catalyzed cross coupling, were performed on a siloxane polymer. This led to the formation of new; highly functionalized polysiloxanes that exhibit second-order nonlinear optical and photoconductive properties. Relatively efficient formation of the stilbene moieties produced siloxane polymers in which each repeat unit bears a charge transporting moiety and an arylamine-based NLO chromophore.

Original language	English (US)
Pages (from-to)	445-446
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	39
Issue number	2
State	Published - Aug 1 1998
Externally published	Yes

All Science Journal Classification (ASJC) codes

Polymers and Plastics

Cite this

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abstract = "A series of three highly efficient reactions, Pt-catalyzed hydrosilation, regiospecific bromination, and Pd-catalyzed cross coupling, were performed on a siloxane polymer. This led to the formation of new; highly functionalized polysiloxanes that exhibit second-order nonlinear optical and photoconductive properties. Relatively efficient formation of the stilbene moieties produced siloxane polymers in which each repeat unit bears a charge transporting moiety and an arylamine-based NLO chromophore.",

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year = "1998",

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AU - Pius, Silvester M.

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Y1 - 1998/8/1

N2 - A series of three highly efficient reactions, Pt-catalyzed hydrosilation, regiospecific bromination, and Pd-catalyzed cross coupling, were performed on a siloxane polymer. This led to the formation of new; highly functionalized polysiloxanes that exhibit second-order nonlinear optical and photoconductive properties. Relatively efficient formation of the stilbene moieties produced siloxane polymers in which each repeat unit bears a charge transporting moiety and an arylamine-based NLO chromophore.

AB - A series of three highly efficient reactions, Pt-catalyzed hydrosilation, regiospecific bromination, and Pd-catalyzed cross coupling, were performed on a siloxane polymer. This led to the formation of new; highly functionalized polysiloxanes that exhibit second-order nonlinear optical and photoconductive properties. Relatively efficient formation of the stilbene moieties produced siloxane polymers in which each repeat unit bears a charge transporting moiety and an arylamine-based NLO chromophore.

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M3 - Conference article

AN - SCOPUS:0032136524

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JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 2

ER -

Synthesis of polysiloxanes bearing di- or triarylamines and NLO chromophores

Abstract

All Science Journal Classification (ASJC) codes

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