The behavior of mixed-metal oxides: Structural and electronic properties of Ce1-xCaxO2 and Ce1-xCa xO2-x

Joś A. Rodriguez; Xianqin Wang; Jonathan C. Hanson; Gang Liu; Ana Iglesias-Juez; Marcos Fernández-García

doi:10.1063/1.1601595

The behavior of mixed-metal oxides: Structural and electronic properties of Ce_1-xCa_xO₂ and Ce_1-xCa _xO_2-x

Joś A. Rodriguez
, Xianqin Wang
, Jonathan C. Hanson
, Gang Liu
, Ana Iglesias-Juez
, Marcos Fernández-García

Research output: Contribution to journal › Article › peer-review

124 Scopus citations

Abstract

A study was performed on the structural and electronic properties of Ce-Ca mixed-metal oxides. The techniques used were synchrotron-based time-resolved x-ray diffraction (TR-XRD), x-ray absorption near edge spectroscopy (XANES), Raman spectroscopy (RS), and first-principles density functional (DF) calculations. The results showed that doping with calcium induces relatively minor variations in the cell dimensions of ceria.

Original language	English (US)
Pages (from-to)	5659-5669
Number of pages	11
Journal	Journal of Chemical Physics
Volume	119
Issue number	11
DOIs	https://doi.org/10.1063/1.1601595
State	Published - Sep 15 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.1601595

Cite this

@article{36e6bdb01b7442c7a34fa4801bc5e50e,

title = "The behavior of mixed-metal oxides: Structural and electronic properties of Ce1-xCaxO2 and Ce1-xCa xO2-x",

abstract = "A study was performed on the structural and electronic properties of Ce-Ca mixed-metal oxides. The techniques used were synchrotron-based time-resolved x-ray diffraction (TR-XRD), x-ray absorption near edge spectroscopy (XANES), Raman spectroscopy (RS), and first-principles density functional (DF) calculations. The results showed that doping with calcium induces relatively minor variations in the cell dimensions of ceria.",

author = "Rodriguez, \{Jo{\'s} A.\} and Xianqin Wang and Hanson, \{Jonathan C.\} and Gang Liu and Ana Iglesias-Juez and Marcos Fern{\'a}ndez-Garc{\'i}a",

year = "2003",

month = sep,

day = "15",

doi = "10.1063/1.1601595",

language = "English (US)",

volume = "119",

pages = "5659--5669",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "11",

}

TY - JOUR

T1 - The behavior of mixed-metal oxides

T2 - Structural and electronic properties of Ce1-xCaxO2 and Ce1-xCa xO2-x

AU - Rodriguez, Joś A.

AU - Wang, Xianqin

AU - Hanson, Jonathan C.

AU - Liu, Gang

AU - Iglesias-Juez, Ana

AU - Fernández-García, Marcos

PY - 2003/9/15

Y1 - 2003/9/15

N2 - A study was performed on the structural and electronic properties of Ce-Ca mixed-metal oxides. The techniques used were synchrotron-based time-resolved x-ray diffraction (TR-XRD), x-ray absorption near edge spectroscopy (XANES), Raman spectroscopy (RS), and first-principles density functional (DF) calculations. The results showed that doping with calcium induces relatively minor variations in the cell dimensions of ceria.

AB - A study was performed on the structural and electronic properties of Ce-Ca mixed-metal oxides. The techniques used were synchrotron-based time-resolved x-ray diffraction (TR-XRD), x-ray absorption near edge spectroscopy (XANES), Raman spectroscopy (RS), and first-principles density functional (DF) calculations. The results showed that doping with calcium induces relatively minor variations in the cell dimensions of ceria.

UR - https://www.scopus.com/pages/publications/0142023783

UR - https://www.scopus.com/pages/publications/0142023783#tab=citedBy

U2 - 10.1063/1.1601595

DO - 10.1063/1.1601595

M3 - Article

AN - SCOPUS:0142023783

SN - 0021-9606

VL - 119

SP - 5659

EP - 5669

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 11

ER -

The behavior of mixed-metal oxides: Structural and electronic properties of Ce_1-xCa_xO₂ and Ce_1-xCa _xO_2-x

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this