TY - JOUR
T1 - The energetics of cubic zirconia from solution calorimetry of yttria- and calcia-stabilized zirconia
AU - Molodetsky, Irina
AU - Navrotsky, Alexandra
AU - Lajavardi, Manoucher
AU - Brune, Alicia
N1 - Copyright:
Copyright 2021 Elsevier B.V., All rights reserved.
PY - 1998
Y1 - 1998
N2 - High-temperature solution calorimetry of monoclinic zirconia, yttria- and calcia-stabilized zirconia cubic solution (m-ZrO2, YSZ and CSZ, respectively) was performed in lead borate (2 PbO · B2O3) at 975 K and 1045 K. Two independent data sets of enthalpy of solution of stabilized zirconia show that the enthalpy of the monoclinic-to-cubic phase transition of zirconia is ΔH (m → c) = +13.5±2.2 kJ/mol. This is in agreement with an estimated value of +12.24 kJ/mol for this transition [1].
AB - High-temperature solution calorimetry of monoclinic zirconia, yttria- and calcia-stabilized zirconia cubic solution (m-ZrO2, YSZ and CSZ, respectively) was performed in lead borate (2 PbO · B2O3) at 975 K and 1045 K. Two independent data sets of enthalpy of solution of stabilized zirconia show that the enthalpy of the monoclinic-to-cubic phase transition of zirconia is ΔH (m → c) = +13.5±2.2 kJ/mol. This is in agreement with an estimated value of +12.24 kJ/mol for this transition [1].
KW - Phase transition
KW - Solution calorimetry
KW - Stabilized zirconia
KW - Zirconia
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U2 - 10.1524/zpch.1998.207.part_1_2.059
DO - 10.1524/zpch.1998.207.part_1_2.059
M3 - Article
AN - SCOPUS:0002627862
SN - 0942-9352
VL - 207
SP - 59
EP - 65
JO - Zeitschrift fur Physikalische Chemie
JF - Zeitschrift fur Physikalische Chemie
IS - 1-2
ER -