The formation of singlet molecular oxygen in the interaction of chlorine dioxide with ozone

Yu S. Chertova, E. V. Avzyanova, K. K. Timergazin, A. F. Khalizov, V. V. Shereshovets, U. B. Imashev

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

The formation of singlet oxygen in the interaction of chlorine dioxide with ozone in CCl4 was proved and its yield was determined by the IR chemiluminescence method. The yield of 1O2 in this reaction strongly depended on the ratio between the initial reagent concentrations and might reach 150%. This led us to suggest a radical-chain mechanism of the reaction. Possible paths of oxygen formation in the reaction were considered.

Original languageEnglish (US)
Pages (from-to)S473-S475
JournalRussian Journal of Physical Chemistry A
Volume74
Issue numberSUPPL. 3
StatePublished - 2000
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

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