The formation of singlet molecular oxygen in the interaction of chlorine dioxide with ozone

Yu S. Chertova; E. V. Avzyanova; K. K. Timergazin; A. F. Khalizov; V. V. Shereshovets; U. B. Imashev

The formation of singlet molecular oxygen in the interaction of chlorine dioxide with ozone

Yu S. Chertova, E. V. Avzyanova, K. K. Timergazin, A. F. Khalizov, V. V. Shereshovets, U. B. Imashev

Research output: Contribution to journal › Article › peer-review

Abstract

The formation of singlet oxygen in the interaction of chlorine dioxide with ozone in CCl₄ was proved and its yield was determined by the IR chemiluminescence method. The yield of ¹O₂ in this reaction strongly depended on the ratio between the initial reagent concentrations and might reach 150%. This led us to suggest a radical-chain mechanism of the reaction. Possible paths of oxygen formation in the reaction were considered.

Original language	English (US)
Pages (from-to)	S473-S475
Journal	Russian Journal of Physical Chemistry A
Volume	74
Issue number	SUPPL. 3
State	Published - 2000
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry

Cite this

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title = "The formation of singlet molecular oxygen in the interaction of chlorine dioxide with ozone",

abstract = "The formation of singlet oxygen in the interaction of chlorine dioxide with ozone in CCl4 was proved and its yield was determined by the IR chemiluminescence method. The yield of 1O2 in this reaction strongly depended on the ratio between the initial reagent concentrations and might reach 150%. This led us to suggest a radical-chain mechanism of the reaction. Possible paths of oxygen formation in the reaction were considered.",

author = "Chertova, {Yu S.} and Avzyanova, {E. V.} and Timergazin, {K. K.} and Khalizov, {A. F.} and Shereshovets, {V. V.} and Imashev, {U. B.}",

year = "2000",

language = "English (US)",

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T1 - The formation of singlet molecular oxygen in the interaction of chlorine dioxide with ozone

AU - Chertova, Yu S.

AU - Avzyanova, E. V.

AU - Timergazin, K. K.

AU - Khalizov, A. F.

AU - Shereshovets, V. V.

AU - Imashev, U. B.

PY - 2000

Y1 - 2000

N2 - The formation of singlet oxygen in the interaction of chlorine dioxide with ozone in CCl4 was proved and its yield was determined by the IR chemiluminescence method. The yield of 1O2 in this reaction strongly depended on the ratio between the initial reagent concentrations and might reach 150%. This led us to suggest a radical-chain mechanism of the reaction. Possible paths of oxygen formation in the reaction were considered.

AB - The formation of singlet oxygen in the interaction of chlorine dioxide with ozone in CCl4 was proved and its yield was determined by the IR chemiluminescence method. The yield of 1O2 in this reaction strongly depended on the ratio between the initial reagent concentrations and might reach 150%. This led us to suggest a radical-chain mechanism of the reaction. Possible paths of oxygen formation in the reaction were considered.

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M3 - Article

AN - SCOPUS:0034346914

SN - 0036-0244

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JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

IS - SUPPL. 3

ER -

The formation of singlet molecular oxygen in the interaction of chlorine dioxide with ozone

Abstract

All Science Journal Classification (ASJC) codes

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