The formation of singlet oxygen in the interaction of chlorine dioxide with ozone in CCl4 was proved and its yield was determined by the IR chemiluminescence method. The yield of 1O2 in this reaction strongly depended on the ratio between the initial reagent concentrations and might reach 150%. This led us to suggest a radical-chain mechanism of the reaction. Possible paths of oxygen formation in the reaction were considered.
|Original language||English (US)|
|Journal||Russian Journal of Physical Chemistry A|
|Issue number||SUPPL. 3|
|State||Published - 2000|
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry