Thermal ignition phenomena in chain‐addition copolymerizations

D. H. Sebastian; J. A. Biesenberger

doi:10.1002/app.1979.070230303

Thermal ignition phenomena in chain‐addition copolymerizations

D. H. Sebastian, J. A. Biesenberger

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Thermal ignition theory has been extended to include free‐radical copolymerizations resulting in dimensionless criteria for runaway and ignition. These criteria were verified by computer simulation and preliminary experimentation. Approximate, but greatly simplified, material and energy balances describing nonisothermal copolymerizations were developed which are similar in form to those describing nonisothermal homopolymerizations. Regions of close agreement, as well as disagreement, between conversion and temperature histories from these approximations and those from the exact balances are described.

Original language	English (US)
Pages (from-to)	661-686
Number of pages	26
Journal	Journal of Applied Polymer Science
Volume	23
Issue number	3
DOIs	https://doi.org/10.1002/app.1979.070230303
State	Published - Feb 1 1979
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry
Surfaces, Coatings and Films
Polymers and Plastics
Materials Chemistry

Access to Document

10.1002/app.1979.070230303

Cite this

@article{d0e7d8d870974590b69f79896e2b860f,

title = "Thermal ignition phenomena in chain‐addition copolymerizations",

abstract = "Thermal ignition theory has been extended to include free‐radical copolymerizations resulting in dimensionless criteria for runaway and ignition. These criteria were verified by computer simulation and preliminary experimentation. Approximate, but greatly simplified, material and energy balances describing nonisothermal copolymerizations were developed which are similar in form to those describing nonisothermal homopolymerizations. Regions of close agreement, as well as disagreement, between conversion and temperature histories from these approximations and those from the exact balances are described.",

author = "Sebastian, {D. H.} and Biesenberger, {J. A.}",

year = "1979",

month = feb,

day = "1",

doi = "10.1002/app.1979.070230303",

language = "English (US)",

volume = "23",

pages = "661--686",

journal = "Journal of Applied Polymer Science",

issn = "0021-8995",

publisher = "John Wiley and Sons Inc.",

number = "3",

}

TY - JOUR

T1 - Thermal ignition phenomena in chain‐addition copolymerizations

AU - Sebastian, D. H.

AU - Biesenberger, J. A.

PY - 1979/2/1

Y1 - 1979/2/1

N2 - Thermal ignition theory has been extended to include free‐radical copolymerizations resulting in dimensionless criteria for runaway and ignition. These criteria were verified by computer simulation and preliminary experimentation. Approximate, but greatly simplified, material and energy balances describing nonisothermal copolymerizations were developed which are similar in form to those describing nonisothermal homopolymerizations. Regions of close agreement, as well as disagreement, between conversion and temperature histories from these approximations and those from the exact balances are described.

AB - Thermal ignition theory has been extended to include free‐radical copolymerizations resulting in dimensionless criteria for runaway and ignition. These criteria were verified by computer simulation and preliminary experimentation. Approximate, but greatly simplified, material and energy balances describing nonisothermal copolymerizations were developed which are similar in form to those describing nonisothermal homopolymerizations. Regions of close agreement, as well as disagreement, between conversion and temperature histories from these approximations and those from the exact balances are described.

UR - http://www.scopus.com/inward/record.url?scp=0018431248&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0018431248&partnerID=8YFLogxK

U2 - 10.1002/app.1979.070230303

DO - 10.1002/app.1979.070230303

M3 - Article

AN - SCOPUS:0018431248

SN - 0021-8995

VL - 23

SP - 661

EP - 686

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 3

ER -

Thermal ignition phenomena in chain‐addition copolymerizations

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this