Thermochemistry is not a lower bound to the activation energy of endothermic reactions: A kinetic study of the gas-phase reaction of atomi-chlorine with ammonia

Keyphrases

• Gas-phase Reactions 100%
• Ammonia 100%
• Chlorine 100%
• Activation Energy 100%
• Endothermic Reaction 100%
• Thermochemistry 100%
• Kinetic Study 100%
• NH 3 100%
• Laser Photolysis 33%
• Pseudo-first Order 33%
• First-order Conditions 33%
• Fluorescence Method 33%
• Transition State Theory 33%
• Cm(III) 33%
• Equilibrium Constant 33%
• Carbon Tetrachloride 33%
• Time-resolved 33%
• Cl Atoms 33%
• Forward Rate 33%
• Excimer Laser 33%
• Arrhenius Parameters 33%
• Confidence Limits 33%
• Potential Energy Surface 33%
• Constant Final Yield 33%
• Reverse Process 33%
• Endothermicity 33%
• Resonance Fluorescence 33%
• Transition State 33%
• MPWB1K 33%
• Negative Activation Energy 33%

Chemistry

• Gas Phase Reaction 100%
• Rate Constant 100%
• Reaction Activation Energy 100%
• Thermochemistry 100%
• Kinetic Study 100%
• Photolysis 33%
• Ground State 33%
• Transition State Theory 33%
• Hydrogen 33%
• Equilibrium Constant 33%
• Excimer 33%
• Potential Energy Surface 33%
• Transition State 33%
• Negative Activation Energy 33%
• Resonance Fluorescence 33%