Unprecedented spin localisation in a metal-metal bonded dirhenium complex

Yong Yan; Joel T. Mague; James P. Donahue; Stephen Sproules

doi:10.1039/c4cc09397f

Unprecedented spin localisation in a metal-metal bonded dirhenium complex

Yong Yan, Joel T. Mague, James P. Donahue, Stephen Sproules

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The molecular and electronic structure of edge-sharing bioctahedral [N(n-Bu)₄]₃[Re₂(mnt)₅] is reported here. Despite the short intermetal bond length of 2.6654(2) Å with computed bond order of 1.2, the unpaired electron is localised by the asymmetric ligand distribution, as demonstrated by its remarkable EPR spectrum. This journal is

Original language	English (US)
Pages (from-to)	5482-5485
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	25
DOIs	https://doi.org/10.1039/c4cc09397f
State	Published - Mar 28 2015
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Unprecedented spin localisation in a metal-metal bonded dirhenium complex",

abstract = "The molecular and electronic structure of edge-sharing bioctahedral [N(n-Bu)4]3[Re2(mnt)5] is reported here. Despite the short intermetal bond length of 2.6654(2) {\AA} with computed bond order of 1.2, the unpaired electron is localised by the asymmetric ligand distribution, as demonstrated by its remarkable EPR spectrum. This journal is",

author = "Yong Yan and Mague, {Joel T.} and Donahue, {James P.} and Stephen Sproules",

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year = "2015",

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doi = "10.1039/c4cc09397f",

language = "English (US)",

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T1 - Unprecedented spin localisation in a metal-metal bonded dirhenium complex

AU - Yan, Yong

AU - Mague, Joel T.

AU - Donahue, James P.

AU - Sproules, Stephen

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2015/3/28

Y1 - 2015/3/28

N2 - The molecular and electronic structure of edge-sharing bioctahedral [N(n-Bu)4]3[Re2(mnt)5] is reported here. Despite the short intermetal bond length of 2.6654(2) Å with computed bond order of 1.2, the unpaired electron is localised by the asymmetric ligand distribution, as demonstrated by its remarkable EPR spectrum. This journal is

AB - The molecular and electronic structure of edge-sharing bioctahedral [N(n-Bu)4]3[Re2(mnt)5] is reported here. Despite the short intermetal bond length of 2.6654(2) Å with computed bond order of 1.2, the unpaired electron is localised by the asymmetric ligand distribution, as demonstrated by its remarkable EPR spectrum. This journal is

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Unprecedented spin localisation in a metal-metal bonded dirhenium complex

Abstract

All Science Journal Classification (ASJC) codes

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